Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3](X= B, C, N) units
Nonlinear optical (NLO) crystals serve as the pivotal core materials for laser frequency
conversion and play an indispensable role in various areas such as information technology …
conversion and play an indispensable role in various areas such as information technology …
Computer‐Aided Development of New Nonlinear Optical Materials
H Wang, M Mutailipu, Z Yang, S Pan… - Angewandte Chemie, 2024 - Wiley Online Library
Exploring new nonlinear optical (NLO) materials is an urgent need for advanced
photoelectric technologies. However, the discovery of new materials with targeted properties …
photoelectric technologies. However, the discovery of new materials with targeted properties …
Stereochemically Active Lone-Pair Containing Metal Substitution in Polar Axis toward a Giant Phase-Matchable Optical Nonlinear Silicate Crystal Li3(OH)PbSiO4
Y Yang, Y **ao, B Li, YG Chen, P Guo… - Journal of the …, 2023 - ACS Publications
Atoms in special lattice sites can play a crucial role in realizing materials properties, which is
long pursued but difficult to control. Herein, by adopting a stereochemically active lone-pair …
long pursued but difficult to control. Herein, by adopting a stereochemically active lone-pair …
Zn2HgP2S8: A Wide Bandgap Hg‐Based Infrared Nonlinear Optical Material with Large Second‐Harmonic Generation Response
Hg‐based chalcogenides, as good candidates for the exploration of high‐performance
infrared (IR) nonlinear optical (NLO) materials, usually exhibit strong NLO effects, but narrow …
infrared (IR) nonlinear optical (NLO) materials, usually exhibit strong NLO effects, but narrow …
Quadruple‐Bidentate Nitrate‐Ligated A2Hg(NO3)4 (A=K, Rb): Strong Second‐Harmonic Generation and Sufficient Birefringence
The design of efficient nonlinear optical (NLO) crystals continues to pose significant
challenges due to the difficulty of assembling polar NLO‐active modules in an optimal …
challenges due to the difficulty of assembling polar NLO‐active modules in an optimal …
Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation
PF Li, CL Hu, YF Li, JG Mao, F Kong - Journal of the American …, 2024 - ACS Publications
Sulfate crystals are often criticized for their low birefringence. The small anisotropic SO4
group is becoming the biggest bottleneck hindering the application of sulfates in optical …
group is becoming the biggest bottleneck hindering the application of sulfates in optical …
Ultrashort Phase‐Matching Wavelength and Strong Second‐Harmonic Generation in Deep‐UV‐Transparent Oxyfluorides by Covalency Reduction
Y Hu, C Wu, X Jiang, K Duanmu, Z Huang… - Angewandte …, 2023 - Wiley Online Library
The development of urgently‐needed ultraviolet (UV)/deep‐UV nonlinear optical (NLO)
materials has been hindered by contradictory requirements of the microstructure, in …
materials has been hindered by contradictory requirements of the microstructure, in …
Beyond π–π Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates
The design of noncentrosymmetric (NCS) solid state materials, specifically how to break
inversion symmetry between enantiomers, has intrigued chemists, physicists, and materials …
inversion symmetry between enantiomers, has intrigued chemists, physicists, and materials …
Ultraviolet crystal with strong optical nonlinearity by creating halogen-centered secondary building blocks
X Shi, A Tudi, M Gai, Z Yang, S Han… - Chemistry of …, 2023 - ACS Publications
Designing new ultraviolet nonlinear optical (NLO) crystals with strong second-harmonic
generation (SHG) response and a deep ultraviolet cutoff edge is an unremitting pursuit of …
generation (SHG) response and a deep ultraviolet cutoff edge is an unremitting pursuit of …
Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2) ZnX 3 (X= Cl, Br, I)
J Chen, HY Wu, MB Xu, MC Wang, QQ Chen… - Inorganic Chemistry …, 2024 - pubs.rsc.org
In the quest for organic–inorganic metal halides (OIMHs) that harmoniously combine large
second harmonic generation (SHG) efficiency with broad bandgaps, our study introduces a …
second harmonic generation (SHG) efficiency with broad bandgaps, our study introduces a …