Metal–organic network-forming glasses
The crystal–liquid–glass phase transition of coordination polymers (CPs) and metal–organic
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …
frameworks (MOFs) offers attractive opportunities as a new class of amorphous materials …
A review on the vitrification of metal coordination compounds and their photonic applications
MA Ali, X Liu, J Qiu - Journal of Non-Crystalline Solids, 2022 - Elsevier
The vitrification of metal coordination compounds (MCC) leads to the emerging of a new
family of glass with unique structures and properties. In this review, we discuss the recent …
family of glass with unique structures and properties. In this review, we discuss the recent …
The glass transition in the high-density amorphous Zn/Co-ZIF-4
The high-density amorphous phases (HDAs) of bimetallic zeolitic imidazolate frameworks
(Zn/Co-ZIF-4) were prepared. The temperature dependence of the isobaric heat capacity …
(Zn/Co-ZIF-4) were prepared. The temperature dependence of the isobaric heat capacity …
Recent progress of amorphous and glassy coordination polymers
In recent decades, the amorphous state of crystalline coordination polymers (CPs)
constructed from metal ions and molecular bridging ligands via coordination bonds, has …
constructed from metal ions and molecular bridging ligands via coordination bonds, has …
Order-to-Disorder Transition in a Zirconium-Based Metal–Organic Framework
DUT-67 is a Zr-based metal–organic framework (MOF) that incorporates thiophene
dicarboxylic acid linkers. In this study, we observed that DUT-67 underwent a striking …
dicarboxylic acid linkers. In this study, we observed that DUT-67 underwent a striking …
The atomic structure and mechanical properties of ZIF-4 under high pressure: ab Initio calculations
Z Shi, K Weng, N Li - Molecules, 2022 - mdpi.com
The effects of pressure on the structural and electronic properties and the ionic configuration
of ZIF-4 were investigated through the first-principles method based on the density functional …
of ZIF-4 were investigated through the first-principles method based on the density functional …
Phase diagram of ZIF-4 from computer simulations
E Méndez, R Semino - Journal of Materials Chemistry A, 2024 - pubs.rsc.org
Well-tempered metadynamics simulations are employed to explore the phase diagram of ZIF-
4, a porous crystalline metal–organic framework of industrial relevance. Despite the vast …
4, a porous crystalline metal–organic framework of industrial relevance. Despite the vast …
Fabrication of durable superhydrophobic stainless steel mesh with nano/micro flower-like morphologies for self-cleaning and efficient oil/water separation
C Xu, Y Luo, L Zhou, Y Bi, H Sun - Journal of Bionic Engineering, 2022 - Springer
How to fabricate durable superhydrophobic materials for cyclic oil/water separation to solve
oil-induced pollutions is still a problem. Herein, we fabricated a durable Superhydrophobic …
oil-induced pollutions is still a problem. Herein, we fabricated a durable Superhydrophobic …
[HTML][HTML] Structural integrity, meltability, and variability of thermal properties in the mixed-linker zeolitic imidazolate framework ZIF-62
Metal–organic framework (MOF) glasses have emerged as a new class of melt-quenched
glasses; however, so far, all MOF glass production has remained at lab-scale; future …
glasses; however, so far, all MOF glass production has remained at lab-scale; future …
Impact of 1-methylimidazole on crystal formation, phase transitions, and glass formation in a zeolitic imidazolate framework
We show that 1-methylimidazole (1-MeIm) can act as a modulator for the synthesis of the
zeolitic imidazolate framework ZIF-4 [Zn (Im) 2], since it affects the particle size, size …
zeolitic imidazolate framework ZIF-4 [Zn (Im) 2], since it affects the particle size, size …