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Strategies towards single-chain magnets
Single-chain magnets (SCM) are a novel class of molecular magnetic materials exhibiting
slow magnetic relaxation, which arises from large uniaxial type magnetic anisotropy, strong …
slow magnetic relaxation, which arises from large uniaxial type magnetic anisotropy, strong …
Magnetic assemblies based on Mn (III) salen analogues
H Miyasaka, A Saitoh, S Abe - Coordination Chemistry Reviews, 2007 - Elsevier
Assembled Mn (III) salen-type quadridentate Schiff-base (SB) complexes,[MnIII (SB)] n+, with
various metal-containing/non-metal building blocks and their synthetic strategies are …
various metal-containing/non-metal building blocks and their synthetic strategies are …
Single-molecule magnet engineering: building-block approaches
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …
the constituent metal ion building blocks. Although this general approach does not seem to …
Design of single chain magnets through cyanide-bearing six-coordinate complexes
The design and preparation of stable cyanide-bearing six-coordinate complexes of formula
[MIII (L)(CN) x](x+ l− m)−(M= trivalent transition metal ion and L= polydentate blocking …
[MIII (L)(CN) x](x+ l− m)−(M= trivalent transition metal ion and L= polydentate blocking …
Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII−FeIII−MnIII Trinuclear Single-Molecule Magnet with an ST = 9/2 Spin Ground …
The cyano-bridged trinuclear compound,(NEt4)[Mn2 (salmen) 2 (MeOH) 2Fe (CN)
6](1)(salmen2-= rac-N, N '-(1-methylethylene) bis (salicylideneiminate)), reported previously …
6](1)(salmen2-= rac-N, N '-(1-methylethylene) bis (salicylideneiminate)), reported previously …
Material applications for salen frameworks
Salens are among the most widely studied ligands in chemistry. They are primarily applied
in homogeneous catalysis, a use that helps to increase our knowledge of environmentally …
in homogeneous catalysis, a use that helps to increase our knowledge of environmentally …
Single-molecule magnets: a molecular approach to nanoscale magnetic materials
A brief survey is provided of single-molecule magnets (SMMs), or molecular nanomagnets.
The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= various) family of SMMs continues to be the …
The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= various) family of SMMs continues to be the …
Rational design of single-molecule magnets: a supramolecular approach
T Glaser - Chemical Communications, 2011 - pubs.rsc.org
Since the discovery that Mn121212OAc acts as a single-molecule magnet (SMM), an
increasing number of transition metal complexes have been demonstrated to behave as …
increasing number of transition metal complexes have been demonstrated to behave as …
Heterometallic [Mn5‐Ln4] Single‐Molecule Magnets with High Anisotropy Barriers
The reaction of [Mn6O2 (Piv) 10 (4‐Me‐py) 2.5 (PivH) 1.5](1)(py: pyridine, Piv: pivilate) with
N‐methyldiethanolamine (mdeaH2) and Ln (NO3) 3⋅ 6 H2O in MeCN leads to a series of …
N‐methyldiethanolamine (mdeaH2) and Ln (NO3) 3⋅ 6 H2O in MeCN leads to a series of …
Heterodinuclear Cu− Tb single-molecule magnet
A strictly heterodinuclear Cu− Tb complex [LCu (O2COMe) Tb (thd) 2] made with a Schiff
base L, thd, and monomethylcarbonate ligands [L2-= N, N '-2, 2-dimethylpropylenedi (3 …
base L, thd, and monomethylcarbonate ligands [L2-= N, N '-2, 2-dimethylpropylenedi (3 …