Transient directing ligands for selective metal-catalysed C–H activation
C–H activation is a 'simple-to-complex'transformation that nature has perfected over millions
of years of evolution. Transition-metal-catalysed C–H activation has emerged as an …
of years of evolution. Transition-metal-catalysed C–H activation has emerged as an …
Transient Ligand‐Enabled Transition Metal‐Catalyzed C− H Functionalization
Transition metal‐catalyzed C− H bond functionalization is among the most efficient and
powerful strategies in synthetic organic chemistry to derivatize otherwise inert sites of …
powerful strategies in synthetic organic chemistry to derivatize otherwise inert sites of …
Transient imines as 'next generation'directing groups for the catalytic functionalisation of C–H bonds in a single operation
C–H functionalisation promises a paradigm shift in synthetic planning. However, the
additional steps often required to install and remove directing groups currently detract from …
additional steps often required to install and remove directing groups currently detract from …
Transient directing groups in metal− organic cooperative catalysis
The direct functionalization of C− H bonds is among the most fundamental chemical
transformations in organic synthesis. However, when the innate reactivity of the substrate …
transformations in organic synthesis. However, when the innate reactivity of the substrate …
Combining transition metals and transient directing groups for C–H functionalizations
In the domain of synthetic chemistry, C–H bond activation has always remained in the
spotlight for researchers over the last few decades. Although different strategies have been …
spotlight for researchers over the last few decades. Although different strategies have been …
Advances in development of C–H activation/functionalization using a catalytic directing group
The transition metal catalyzed direct site‐selective carbon–hydrogen functionalization is
ubiquitous in organic synthesis and has reached an impressive level of sophistication and …
ubiquitous in organic synthesis and has reached an impressive level of sophistication and …
Monodentate Transient Directing Group Assisted Ruthenium(II)-Catalyzed Direct ortho-C–H Imidation of Benzaldehydes for Diverse Synthesis of Quinazoline and …
Y Wu, N Liu, M Qi, H Qiao, X Lu, L Ma, Y Zhou… - Organic …, 2021 - ACS Publications
2-Fluoro-5-(trifluoromethyl) aniline was found to be a suitable monodentate transient
directing group (MonoTDG) to enable Ru (II)-catalyzed intermolecular direct ortho-C (sp2)–H …
directing group (MonoTDG) to enable Ru (II)-catalyzed intermolecular direct ortho-C (sp2)–H …
Transition Metal-Catalyzed CH Activation via Imine-Based Transient Directing Group Strategy
In the past decades, transition metal-catalyzed C—H activation has experienced
tremendous growth and revolutionized the field of organic synthesis. Several elegant …
tremendous growth and revolutionized the field of organic synthesis. Several elegant …
Manganese-Catalyzed ortho-CH Amidation of Weakly Coordinating Aromatic Ketones
X Kong, B Xu - Organic Letters, 2018 - ACS Publications
An efficient manganese-catalyzed ortho-CH amidation of weakly coordinating aromatic
ketones using the readily available sulfonyl azide as the amination reagent is developed …
ketones using the readily available sulfonyl azide as the amination reagent is developed …
Cp*Co(III)‐Catalyzed o‐Amidation of Benzaldehydes with Dioxazolones Using Transient Directing Group Strategy
Transition metal‐catalyzed ortho‐selective C (sp2)− H amidation of weakly coordinating
aldehydes remains limited to precious metals such as Ir, Rh, Ru, etc. Herein, we put forward …
aldehydes remains limited to precious metals such as Ir, Rh, Ru, etc. Herein, we put forward …