Background During the last few decades, progress has been made in manipulating the
architecture of synthetic polymer materials. However, the primary structure—that is, the …

Over the last ten years, the development of synthetic polymers containing controlled
monomer sequences has become a prominent topic in fundamental and applied polymer …

Controlled/living radical polymerization techniques have transformed polymer chemistry in
the last few decades, affording the production of polymers with precise control over both …

Polymer chemists, through advances in controlled polymerization techniques and reliable
post‐functionalization methods, now have the tools to create materials of almost infinite …

The aim of this short perspective article is to sensitize polymer chemists to the importance of
controlling comonomer sequences. During the last twenty years, our scientific community …

An overview is given on the state-of-the-art in synthesis of sequence-controlled and
sequence-defined oligomers and polymers. These materials constitute chains in which …

The monomer units of a polymer can be used to encode a message. This property is used,
for instance, by nature to store genetic information in DNA macromolecules. Therefore …

A new strategy to achieve sequence control in polymer chemistry based on the iterative
application of the versatile Passerini three‐component reaction (P‐3CR) in combination with …

Sequence-defined non-natural polyphosphates were prepared using iterative
phosphoramidite protocols on a polystyrene solid support. Three monomers were used in …

We survey progress in the development of the processes for radical-promoted single-unit
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …