The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Molecular optomechanics approach to surface-enhanced Raman scattering

R Esteban, JJ Baumberg… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Molecular vibrations constitute one of the smallest mechanical oscillators
available for micro-/nanoengineering. The energy and strength of molecular oscillations …

Continuous-wave frequency upconversion with a molecular optomechanical nanocavity

W Chen, P Roelli, H Hu, S Verlekar, SP Amirtharaj… - Science, 2021 - science.org
Coherent upconversion of terahertz and mid-infrared signals into visible light opens new
horizons for spectroscopy, imaging, and sensing but represents a challenge for conventional …

Detecting mid-infrared light by molecular frequency upconversion in dual-wavelength nanoantennas

A Xomalis, X Zheng, R Chikkaraddy, Z Koczor-Benda… - Science, 2021 - science.org
Coherent interconversion of signals between optical and mechanical domains is enabled by
optomechanical interactions. Extreme light-matter coupling produced by confining light to …

Sensing of arbitrary-frequency fields using a quantum mixer

G Wang, YX Liu, JM Schloss, ST Alsid, DA Braje… - Physical Review X, 2022 - APS
Quantum sensors such as spin defects in diamond have achieved excellent performance by
combining high sensitivity with spatial resolution. Unfortunately, these sensors can only …

Hybrid cavity-antenna architecture for strong and tunable sideband-selective molecular Raman scattering enhancement

I Shlesinger, J Vandersmissen, E Oksenberg… - Science …, 2023 - science.org
Plasmon resonances at the surface of metallic antennas allow for extreme enhancement of
Raman scattering. Intrinsic to plasmonics, however, is that extreme field confinement lacks …

Advances in the photon avalanche luminescence of inorganic lanthanide-doped nanomaterials

M Szalkowski, A Kotulska, M Dudek… - Chemical Society …, 2025 - pubs.rsc.org
Photon avalanche (PA)—where the absorption of a single photon initiates a 'chain
reaction'of additional absorption and energy transfer events within a material—is a highly …

Mid-infrared-perturbed molecular vibrational signatures in plasmonic nanocavities

R Chikkaraddy, A Xomalis, LA Jakob… - Light: Science & …, 2022 - nature.com
Recent developments in surface-enhanced Raman scattering (SERS) enable observation of
single-bond vibrations in real time at room temperature. By contrast, mid-infrared (MIR) …

Nanostructure-enhanced infrared spectroscopy

T Tanaka, T Yano, R Kato - Nanophotonics, 2022 - degruyter.com
While infrared spectroscopy is a powerful technique that provides molecular information
such as chemical constituents and chemical structures of analytes, it suffers from low …

Interfering plasmons in coupled nanoresonators to boost light localization and SERS

A Xomalis, X Zheng, A Demetriadou, A Martínez… - Nano …, 2021 - ACS Publications
Plasmonic self-assembled nanocavities are ideal platforms for extreme light localization as
they deliver mode volumes of< 50 nm3. Here we show that high-order plasmonic modes …