Shedding light on bifunctional luminescent spin crossover materials

MK Javed, A Sulaiman, M Yamashita, ZY Li - Coordination Chemistry …, 2022 - Elsevier
The spin crossover (SCO) phenomenon has witnessed remarkable progress in applications
since it was first discovered almost a century ago. Specifically, materials that exhibit SCO …

Synergistic strategies for the synthesis of Fe (II)-based bifunctional fluorescent spin-crossover materials

K Sun, JP Xue, ZS Yao, J Tao - Dalton Transactions, 2022 - pubs.rsc.org
Spin-crossover (SCO) materials have been extensively investigated in the past few decades
with promising applications in a wide range of fields including displays, sensors, and …

A Two‐Dimensional Iron (II) Coordination Polymer with Synergetic Spin‐Crossover and Luminescent Properties

JY Ge, Z Chen, L Zhang, X Liang, J Su… - Angewandte …, 2019 - Wiley Online Library
Abstract A composite material,{[Fe (L)(TPPE) 0.5]⋅ 3 CH3OH} n, has been constructed by
integrating the spin‐crossover (SCO) subunit FeII {diethyl (E, E)‐2, 2′‐[1, 2‐phenyl‐bis …

Rhodamine 6G-labeled pyridyl aroylhydrazone Fe (II) complex exhibiting synergetic spin crossover and fluorescence

J Yuan, SQ Wu, MJ Liu, O Sato… - Journal of the American …, 2018 - ACS Publications
Here, we use a pyridinecarbaldehyde rhodamine 6G hydrazone ligand (L) to synthesize an
Fe (II) complex 1 for the search of new fluorescent-spin crossover (SCO) materials. Single …

Bistable molecular materials with dynamic structures

ZS Yao, Z Tang, J Tao - Chemical communications, 2020 - pubs.rsc.org
The development of molecular materials whose physical properties can be switched
between different states has attracted significant attention for their potential application in …

Interplay between spin-crossover and luminescence in a multifunctional single crystal iron (II) complex: Towards a new generation of molecular sensors

B Benaicha, K Van Do, A Yangui, N Pittala… - Chemical …, 2019 - pubs.rsc.org
We present a new example of a mononuclear iron (II) complex exhibiting a correlated spin-
crossover (SCO) transition and strong fluorescence, whose coordination sphere is saturated …

Mechanism of Coupling of Alcohols and Amines To Generate Aldimines and H2 by a Pincer Manganese Catalyst

J Masdemont, JA Luque-Urrutia, M Gimferrer… - ACS …, 2019 - ACS Publications
Acceptorless dehydrogenative coupling (ADC) of alcohols and amines using a manganese-
based catalyst is able to produce aldimines, which have a wide reactivity, without …

A Smart Molecule Showing Spin Crossover Responsive Aggregation-Induced Emission

C Yi, YS Meng, L Zhao, NT Yao, Q Liu, W Wen… - CCS …, 2023 - chinesechemsoc.org
The utilization of spin crossover (SCO) to modulate the luminescence properties in smart
multifunctional materials and multichannel sensors is promising. However, it is challenging …

Mix and match–controlling the functionality of spin-crossover materials through solid solutions and molecular alloys

MA Halcrow - Dalton Transactions, 2024 - pubs.rsc.org
The influence of dopant molecules on the structure and functionality of spin-crossover (SCO)
materials is surveyed. Two aspects of the topic are well established. Firstly, isomorphous …

Synergetic spin-crossover and luminescent properties in a multifunctional 2D iron (II) coordination polymer

J Wang, M Kong, XJ Song, Y **g, Y Zhao… - Inorganic …, 2022 - ACS Publications
We designed and synthesized a strong fluorescent tetradentate pyridine ligand, 3, 6, 11, 12-
tetra (pyridin-4-yl) dibenzo [a, c] phenazine (TPDP), by covalently grafting pyridyl to …