Ultrahigh molecular weight polyethylene: Catalysis, structure, properties, processing and applications

K Patel, SH Chikkali, S Sivaram - Progress in polymer science, 2020 - Elsevier
Ultrahigh molecular weight polyethylene (UHMWPE) belongs to an emerging class of high-
performance specialty polymers with a unique set of properties and applications. The field …

From multisite polymerization catalysis to sustainable materials and all-polyolefin composites

M Stürzel, S Mihan, R Mülhaupt - Chemical reviews, 2016 - ACS Publications
Since the pioneering advances of Karl Ziegler and Giulio Natta during the early 1950s, a
continuing series of breakthroughs in research and industrial innovations have greatly …

Main group metal polymerisation catalysts

E Fazekas, PA Lowy, MA Rahman… - Chemical Society …, 2022 - pubs.rsc.org
With sustainability at the forefront of current polymerisation research, the typically earth-
abundant, inexpensive and low-toxicity main group metals are attractive candidates for …

Direct production of olefins from syngas with ultrahigh carbon efficiency

H Yu, C Wang, T Lin, Y An, Y Wang, Q Chang… - Nature …, 2022 - nature.com
Syngas conversion serves as a competitive strategy to produce olefins chemicals from
nonpetroleum resources. However, the goal to achieve desirable olefins selectivity with …

Bridging the Gap between Industrial and Well‐Defined Supported Catalysts

C Copéret, F Allouche, KW Chan… - Angewandte Chemie …, 2018 - Wiley Online Library
Many industrial catalysts contain isolated metal sites on the surface of oxide supports.
Although such catalysts have been used in a broad range of processes for more than 40 …

Defect engineering in metal–organic frameworks towards advanced mixed matrix membranes for efficient propylene/propane separation

TH Lee, JG Jung, YJ Kim, JS Roh… - Angewandte Chemie …, 2021 - Wiley Online Library
Highly permselective and durable membrane materials have been sought for energy‐
efficient C3H6/C3H8 separation. Mixed‐matrix membranes (MMMs) comprising a polymer …

Multinuclear olefin polymerization catalysts

M Delferro, TJ Marks - Chemical reviews, 2011 - ACS Publications
1.1. Inspired by Nature In many enzymes, such as ureases (Figure 1), two or more metal
centers are poised in close proximity to activate both electrophilic and nucleophilic …

The search for new‐generation olefin polymerization catalysts: life beyond metallocenes

GJP Britovsek, VC Gibson… - Angewandte Chemie …, 1999 - Wiley Online Library
Even late transition metal complexes function as active and selective catalysts for α‐olefin
polymerization. The discovery of a highly active family of catalysts 1 based on iron, a metal …

Macromolecular architectures by living and controlled/living polymerizations

N Hadjichristidis, H Iatrou, M Pitsikalis… - Progress in Polymer …, 2006 - Elsevier
The discovery of living anionic polymerization by Szwarc 50 years ago opened the way to
the synthesis of model polymers. This ground-breaking discovery inspired many researchers …

Closing the carbon loop in the circular plastics economy

CG Schirmeister, R Mülhaupt - Macromolecular rapid …, 2022 - Wiley Online Library
Today, plastics are ubiquitous in everyday life, problem solvers of modern technologies, and
crucial for sustainable development. Yet the surge in global demand for plastics of the …