Unlocking the computational design of metal–organic cages
Metal–organic cages are macrocyclic structures that can possess an intrinsic void that can
hold molecules for encapsulation, adsorption, sensing, and catalysis applications. As metal …
hold molecules for encapsulation, adsorption, sensing, and catalysis applications. As metal …
Tailoring the Asymmetric Structure of NH2‐UiO‐66 Metal‐Organic Frameworks for Light‐promoted Selective and Efficient Gold Extraction and Separation
J Cao, Z Xu, Y Chen, S Li, Y Jiang, L Bai… - Angewandte Chemie …, 2023 - Wiley Online Library
Designing adsorption materials with high adsorption capacities and selectivities is highly
desirable for precious metal recovery. Desorption performance is also particularly crucial for …
desirable for precious metal recovery. Desorption performance is also particularly crucial for …
Directing metallo-supramolecular assembly through complementarity
In chemistry, function and behaviour flow directly from structure. As chemists seek to develop
highly complex functional molecules, we need to harness routes to complex structures. In …
highly complex functional molecules, we need to harness routes to complex structures. In …
Exploiting reduced-symmetry ligands with pyridyl and imidazole donors to construct a second-generation stimuli-responsive heterobimetallic [PdPtL 4] 4+ cage
A new sequential metalation strategy that enables the assembly of a new more robust
reduced symmetry heterobimetallic [PdPtL4] 4+ cage C is reported. By exploiting a low …
reduced symmetry heterobimetallic [PdPtL4] 4+ cage C is reported. By exploiting a low …
A Lantern‐Shaped Pd (II) Cage Constructed from Four Different Low‐Symmetry Ligands with Positional and Orientational Control: An Ancillary Pairings Approach
One of the key challenges of metallo‐supramolecular chemistry is to maintain the ease of
self‐assembly but, at the same time, create structures of increasingly high levels of …
self‐assembly but, at the same time, create structures of increasingly high levels of …
Structural Transformations of Metal–Organic Cages through Tetrazine-Alkene Reactivity
The assembly of metal–organic cages is governed by metal ion coordination preferences
and the geometries of the typically rigid and planar precursor ligands. Pd n L2 n cages are …
and the geometries of the typically rigid and planar precursor ligands. Pd n L2 n cages are …
Diastereoselective Self‐Assembly of Low‐Symmetry PdnL2n Nanocages through Coordination‐Sphere Engineering**
Metal‐organic cages (MOCs) are popular host architectures assembled from ligands and
metal ions/nodes. Assembling structurally complex, low‐symmetry MOCs with anisotropic …
metal ions/nodes. Assembling structurally complex, low‐symmetry MOCs with anisotropic …
Orientational self-sorting in cuboctahedral Pd cages
Cuboctahedral coordination cages of the general formula [Pd12L24] 24+(L= low-symmetry
ligand) were analyzed theoretically and experimentally. With 350 696 potential isomers, the …
ligand) were analyzed theoretically and experimentally. With 350 696 potential isomers, the …
Maximized axial helicity in a Pd 2 L 4 cage: inverse guest size-dependent compression and mesocate isomerism
WM Bloch, S Horiuchi, JJ Holstein, C Drechsler… - Chemical …, 2023 - pubs.rsc.org
Helicity is an archetypal structural motif of many biological systems and provides a basis for
molecular recognition in DNA. Whilst artificial supramolecular hosts are often helical, the …
molecular recognition in DNA. Whilst artificial supramolecular hosts are often helical, the …
Heteroleptic tripalladium (II) cages
JA Findlay, KM Patil, MG Gardiner… - Chemistry–An Asian …, 2022 - Wiley Online Library
There is a concerted attempt to develop self‐assembled metallo‐cages of greater structural
complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts …
complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts …