Hydride Do** Effects on the Structure and Properties of Eight-Electron Rh/Ag Superatoms: The [RhHx@Ag21–x{S2P(OnPr)2}12] (x = 0–2) Series

TH Chiu, JH Liao, YY Wu, JY Chen… - Journal of the …, 2023 - ACS Publications
Three hitherto unknown eight-electron rhodium/silver alloy nanoclusters,[RhAg21 {S2P (O n
Pr) 2} 12](1),[RhHAg20 {S2P (O n Pr) 2} 12](2), and [RhH2Ag19 {S2P (O n Pr) 2} 12](3), have …

Core-Packing-Related Vibrational Properties of Thiol-Protected Gold Nanoclusters and Their Excited-State Behavior

X Yu, WJ Yen, JH Liao, TH Chiu, JY Chen, YJ Chen, S Kahlal… - Nanoscale, 2024 - pubs.rsc.org
This study investigates the effects of metal addition and do** of a 2-electron silver
superatom,[Ag10 {S2P (OiPr) 2} 8](Ag10). When Ag+ is added to Ag10 in THF solution,[Ag11 …

Hydride-containing Ag-and Au-rich 8-electron superatomic icosahedral Cores: A DFT investigation

H Liang, TH Chiu, S Kahlal, JH Liao, CW Liu… - Nanoscale, 2025 - pubs.rsc.org
Following several reports on ligand-protected atom-precise nanoclusters which encapsulate
hydrides as interstitial dopants within their icosahedral core, the stability, structure and …

Structures, Electronic, And Magnetic Properties Of Transition Metal-Inserted H2dbp Clusters

Z Li, SQ Yang, JH Yin, JC Li, S Abbasi - Surface Review and Letters …, 2024 - ideas.repec.org
The configurations, electronic, and magnetic properties of the H2DBP-M clusters have been
investigated via density functional theory. The results reveal that the TM atoms for the …

Assembling Gold Icosahedrons to Superatomic Molecules Mimicking the Bonding Rules in Molecules

Q Yuan, J Gao, Y Zheng, C Xu, L Cheng - Inorganic Chemistry, 2025 - ACS Publications
Icosahedral gold clusters with high-symmetry geometry and magic electronic shells are
potential candidates for cluster-assembling, while their assembling rules are still awaiting …

Structure, electronic and magnetic properties of the AlN clusters encapsulated with transition metals

Z Li, Z Zhao - International Journal of Modern Physics B, 2024 - World Scientific
The metal-doped aluminum nitrides have attracted special attention as new technology-
related materials owing to their combination of fullerene-like and metallic properties. The …