Current status and outlook for ATRP

K Matyjaszewski - European Polymer Journal, 2024 - Elsevier
Atom transfer radical polymerization (ATRP) is one of the most often used controlled radical
polymerization techniques. It employs very small amounts (ppm) of Cu complexes in the …

Better Together: Photoredox/Copper Dual Catalysis in Atom Transfer Radical Polymerization

J Sobieski, A Gorczyński, AM Jazani… - Angewandte Chemie …, 2025 - Wiley Online Library
Abstract Photomediated Atom Transfer Radical Polymerization (photoATRP) is an activator
regeneration method, which allows for the controlled synthesis of well‐defined polymers via …

ATRP with ppb Concentrations of Photocatalysts

HI Coskun, F De Luca Bossa, X Hu… - Journal of the …, 2024 - ACS Publications
In atom transfer radical polymerization (ATRP), dormant alkyl halides are intermittently
activated to form growing radicals in the presence of a CuI/L/X-CuII/L (activator/deactivator) …

Electrochemically mediated atom transfer radical polymerization driven by alternating current

F De Bon, M Fantin, VA Pereira… - Angewandte Chemie …, 2024 - Wiley Online Library
Alternating current (AC) and pulsed electrolysis are gaining traction in electro (organic)
synthesis due to their advantageous characteristics. We employed AC electrolysis in …

Solid-Phase Synthesis of Well-Defined Multiblock Copolymers by Atom Transfer Radical Polymerization

G Szczepaniak, K Kapil, S Adida, K Kim… - Journal of the …, 2024 - ACS Publications
Solid-phase polymer synthesis, historically rooted in peptide synthesis, has evolved into a
powerful method for achieving sequence-controlled macromolecules. This study explores …

Atom transfer radical polymerization

S Harrisson, R Whitfield, A Anastasaki… - Nature Reviews …, 2025 - nature.com
Atom transfer radical polymerization (ATRP) is a synthetic method that harnesses radical
polymerization to yield well-defined polymers of controlled architecture from a wide range of …

[HTML][HTML] Copper and ZnO Dual-Catalyzed Photo-Assisted Depolymerization of Poly (Methyl Methacrylate) without Deoxygenation

M Cvek, AM Jazani, FDL Bossa, R Bernat… - European Polymer …, 2024 - Elsevier
Despite significant advancements in thermal and photothermal depolymerizations, the
success of these techniques relies on tedious deoxygenation procedures. Herein, we report …

Effects of Solvent and Monomer on the Kinetics of Radical Generation in Atom Transfer Radical Polymerization

M Fantin, E Tognella, A Antonello, F Lorandi… - …, 2024 - Wiley Online Library
Unlike classical radical polymerization, the kinetics of atom transfer radical polymerization
show significant solvent dependence, possibly arising from solvent effects on the activation …

Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation

K Kapil, M Sun, TC Lin, H Murata, G Szczepaniak… - Polymer …, 2024 - pubs.rsc.org
Heterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-
effectiveness. Despite the existence of various types of these PCs, their synthesis often …

Advances in the textile industry through surface-initiated reversible deactivation radical polymerization: Exploring the latest advances, opportunities, and future …

K Kisiel, I Zaborniak, P Chmielarz - Polymer, 2024 - Elsevier
Textiles, regardless of their composition–whether natural fibers like cotton and silk or
synthetic materials like polyester and nylon, play a significant role in everyday use across …