Endohedral metallofullerene molecular nanomagnets

Z Hu, S Yang - Chemical Society Reviews, 2024 - pubs.rsc.org
Magnetic lanthanide (Ln) metal complexes exhibiting magnetic bistability can behave as
molecular nanomagnets, also known as single-molecule magnets (SMMs), suitable for …

When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F ** - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Nanoparticle-drug conjugates treating bacterial infections

P Jelinkova, A Mazumdar, VP Sur, S Kociova… - Journal of controlled …, 2019 - Elsevier
The ever increasing scenario of bacterial resistance against commonly available antibiotics
is becoming a global threat of major concern, which necessitates the development of new …

Fullerenes as nanocontainers that stabilize unique actinide species inside: structures, formation, and reactivity

W Cai, CH Chen, N Chen… - Accounts of Chemical …, 2019 - ACS Publications
Conspectus Fullerene carbon cages can encapsulate a wide variety of atoms, ions, clusters,
or small molecules inside, resulting in stable compounds with unusual structures and …

25th anniversary article: 25 years of fullerene research in electron transfer chemistry

S Kirner, M Sekita, DM Guldi - Advanced Materials, 2014 - Wiley Online Library
The past 25 years have served as a test bed for exploring the chemistry and physics, in
general, and the electron transfer chemistry, in particular, of low‐dimensional carbon …

The role of aromaticity in determining the molecular structure and reactivity of (endohedral metallo) fullerenes

M Garcia-Borras, S Osuna, JM Luis, M Swart… - Chemical Society …, 2014 - pubs.rsc.org
The encapsulation of metal clusters in endohedral metallofullerenes (EMFs) takes place in
cages that in most cases are far from being the most stable isomer in the corresponding …

Endohedral Metallofullerenes Based on Spherical Ih-C80 Cage: Molecular Structures and Paramagnetic Properties

T Wang, C Wang - Accounts of Chemical Research, 2014 - ACS Publications
Fullerenes are carbon cages assembled from fused hexagons andpentagons that have
closed networks and conjugated π systems. The curve of the fullerene structure requires that …

A stabilization rule for metal carbido cluster bearing μ3-carbido single-atom-ligand encapsulated in carbon cage

R Guan, J Huang, J ** a variety of metal clusters within carbon cage,
for which the entrapped metal cluster generally keeps its geometric structure (eg, bond …

Titanium-oxide host clusters with exchangeable guests

G Zhang, W Li, C Liu, J Jia, CH Tung… - Journal of the American …, 2018 - ACS Publications
A novel family of water-soluble, polyoxocationic titanium-oxide host–guest clusters are
reported herein. They exhibit an unprecedented hexagonal prismatic core structure for …