Valence-bound anions with polar neutral cores (μ>∼ 2.5 D) can support dipole-bound
excited states below the detachment threshold. These dipole-bound states (DBSs) are …

Molecular anions with polar neutral cores can support highly diffuse dipole-bound states
below their detachment thresholds due to the long-range charge–dipole interaction. Such …

We report photodetachment spectroscopy and high-resolution photoelectron imaging of
para-halogen substituted phenoxide anions, p-XC6H4O–(X= F, Cl, Br, I). The dipole …

Polar molecules can bind an electron in a diffuse orbital due to the charge-dipole interaction.
Electronic excited states of polar molecules can also bind an electron to form core-excited …

Dipole-bound states (DBSs) are diffuse non-valence molecular orbitals of anions where the
electron is bound by the permanent dipole moment of the neutral core. Here, an …

We report the observation of a dipole-bound state (DBS) 659 cm–1 below the electron
detachment threshold of cryogenically cooled deprotonated 4, 4′-biphenol anion (bPh–) …

Dipole-bound states in anions exist when a polar neutral core binds an electron in a diffuse
orbital through charge–dipole interaction. Electronically excited polar neutral cores can also …

The diffuse electron in a dipole-bound state is spatially well separated from the valence
electrons and is known to have negligible effects on the dipole-bound state's molecular …

Negative ions do not possess Rydberg states but can have Rydberg-like nonvalence excited
states near the electron detachment threshold, including dipole-bound states (DBSs) and …

We report an observation of spin–orbit excited dipole-bound states (DBSs) in arginine–
iodide complexes (Arg· I–) by using temperature-dependent, wavelength-resolved “iodide …