Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F ** - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Current status and future developments of endohedral metallofullerenes

X Lu, L Feng, T Akasaka, S Nagase - Chemical Society Reviews, 2012 - pubs.rsc.org
Endohedral metallofullerenes (EMFs), a new class of hybrid molecules formed by
encapsulation of metallic species inside fullerene cages, exhibit unique properties that differ …

Chemistry of endohedral metallofullerenes: the role of metals

X Lu, T Akasaka, S Nagase - Chemical Communications, 2011 - pubs.rsc.org
Recent breakthroughs achieved in the chemical functionalization of endohedral
metallofullerenes (EMFs), especially single crystallographic X-ray characterizations of their …

Trimetallic nitride template endohedral metallofullerenes: discovery, structural characterization, reactivity, and applications

J Zhang, S Stevenson, HC Dorn - Accounts of chemical research, 2013 - ACS Publications
Shortly after the discovery of the carbon fullerene allotrope, C60, researchers recognized
that the hollow spheroidal shape could accommodate metal atoms, or clusters, which quickly …

Structurally Defined Water‐Soluble Metallofullerene Derivatives towards Biomedical Applications

Y Li, R Biswas, WP Kopcha, T Dubroca… - Angewandte …, 2023 - Wiley Online Library
Endohedral metallofullerenes (EMFs) are excellent carriers of rare‐earth element (REE)
ions in biomedical applications because they preclude the release of toxic metal ions …

Carbene additions to fullerenes

M Yamada, T Akasaka, S Nagase - Chemical Reviews, 2013 - ACS Publications
Carbon is the most prominent element of state-of-the-art nanoscience. Kroto, Curl, and
Smalley were awarded the Nobel Prize in Chemistry in 1996 for discovery of fullerenes. 1− 4 …

Rational design on n-type organic materials for high performance organic photovoltaics

CL Chochos, N Tagmatarchis, VG Gregoriou - Rsc Advances, 2013 - pubs.rsc.org
The demand for further optimization of the photovoltaic efficiency has stimulated an intensive
research effort both for new low-band-gap polymeric materials as electron donors and for …

Exploring endohedral metallofullerenes for advanced thin-film device applications toward next-generation electronics

JS Nam, Y Seo, J Han, JW Lee, K Kim… - Chemistry of …, 2023 - ACS Publications
Endohedral metallofullerenes (EMFs) showcase unique properties such as their capacity to
stabilize isolated metal atoms and reactive metal clusters, rendering them highly appealing …

Exohedral functionalization of endohedral metallofullerenes: Interplay between inside and outside

P **, Y Li, S Magagula, Z Chen - Coordination Chemistry Reviews, 2019 - Elsevier
Endohedral metallofullerenes (EMFs) are fullerene cages enclosing various metallic
species. The functionalization of EMFs has remarkably blossomed in recent years, in …