Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes

JO Zoppe, NC Ataman, P Mocny, J Wang… - Chemical …, 2017 - ACS Publications
The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-
CRP) techniques has become a powerful approach to tailor the chemical and physical …

Polymer brushes via surface-initiated controlled radical polymerization: synthesis, characterization, properties, and applications

R Barbey, L Lavanant, D Paripovic, N Schuwer… - Chemical …, 2009 - ACS Publications
Polymer Brushes via Surface-Initiated Controlled Radical Polymerization: Synthesis,
Characterization, Properties, and Applications | Chemical Reviews Recently Viewedclose …

Advances in atomic force microscopy for probing polymer structure and properties

D Wang, TP Russell - Macromolecules, 2018 - ACS Publications
Over the past 30 years, atomic force microscopy (AFM) has played an important role in
elucidating the structure and properties of polymer surfaces. AFM-based techniques have …

Zwitterionic Poly (amino acid methacrylate) Brushes

AM Alswieleh, N Cheng, I Canton… - Journal of the …, 2014 - ACS Publications
A new cysteine-based methacrylic monomer (CysMA) was conveniently synthesized via
selective thia-Michael addition of a commercially available methacrylate-acrylate precursor …

Probing the Collapse Dynamics of Poly(N‐isopropylacrylamide) Brushes by AFM: Effects of Co‐nonsolvency and Grafting Densities

X Sui, Q Chen, MA Hempenius, GJ Vancso - small, 2011 - Wiley Online Library
Collapse of poly (N‐isopropylacrylamide)(PNIPAM) brushes in the mixed solvent system
(water/methanol 50% v/v) is studied by in‐situ atomic‐force microscopy (AFM). PNIPAM …

Tuning the pH sensitivity of poly (methacrylic acid) brushes

N Schüwer, HA Klok - Langmuir, 2011 - ACS Publications
The pH-induced swelling and collapse of surface-tethered, weak polyelectrolyte brushes is
of interest for the development of actuators or to allow pH controlled transport or adsorption …

Polymer brushes: Routes toward mechanosensitive surfaces

J Bünsow, TS Kelby, WTS Huck - Accounts of chemical research, 2010 - ACS Publications
Soft nanotechnology involves both understanding the behavior of soft matter and using
these components to build useful nanoscale structures and devices. However, molecular …

Characterization and molecular engineering of surface-grafted polymer brushes across the length scales by atomic force microscopy

X Sui, S Zapotoczny, EM Benetti, P Schön… - Journal of materials …, 2010 - pubs.rsc.org
With the advent of regulated, surface initiated polymerizations, specifically using controlled
radical approaches, the choice of polymerizable compounds and the control over grafting …

Voltage-induced swelling and deswelling of weak polybase brushes

MP Weir, SY Heriot, SJ Martin, AJ Parnell, SA Holt… - Langmuir, 2011 - ACS Publications
We have investigated a novel method of remotely switching the conformation of a weak
polybase brush using an applied voltage. Surface-grafted polyelectrolyte brushes exhibit …

Design of self-oscillating polymer brushes and control of the dynamic behaviors

T Masuda, AM Akimoto, K Nagase, T Okano… - Chemistry of …, 2015 - ACS Publications
A polymer brush surface with autonomous function has been designed by using a self-
oscillating polymer that we developed. The self-oscillation is induced by chemomechanical …