Earth abundant transition metal complexes as molecular water oxidation catalysts

MA Khan, S Khan, S Sengupta, BN Mongal… - Coordination Chemistry …, 2024 - Elsevier
Coherency of nature has always inspired human to develop, produce and innovate by
imitating it. Photosynthesis is amongst the most efficient bio-chemical reaction nature …

The impact of ligand carboxylates on electrocatalyzed water oxidation

B Das, A Rahaman, A Shatskiy, O Verho… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Fossil fuel shortage and severe climate changes due to global warming have
prompted extensive research on carbon-neutral and renewable energy resources …

A di-copper-peptoid in a noninnocent borate buffer as a fast electrocatalyst for homogeneous water oxidation with low overpotential

G Ruan, P Ghosh, N Fridman… - Journal of the American …, 2021 - ACS Publications
Water electrolysis is a promising approach toward low-cost renewable fuels; however, the
high overpotential and slow kinetics limit its applicability. Studies suggest that either …

Discovery of PF-07265028, A Selective Small Molecule Inhibitor of Hematopoietic Progenitor Kinase 1 (HPK1) for the Treatment of Cancer

RA Gallego, S Cho-Schultz, M Del Bel… - Journal of Medicinal …, 2024 - ACS Publications
Hematopoietic progenitor kinase 1 (HPK1/MAP4K1) represents a high interest target for the
treatment of cancer through an immune-mediated mechanism. Herein we present highlights …

From Ru-bda to Ru-bds: a step forward to highly efficient molecular water oxidation electrocatalysts under acidic and neutral conditions

J Yang, L Wang, S Zhan, H Zou, H Chen… - Nature …, 2021 - nature.com
Significant advances during the past decades in the design and studies of Ru complexes
with polypyridine ligands have led to the great development of molecular water oxidation …

Bioinspired Active Site with a Coordination-Adaptive Organosulfonate Ligand for Catalytic Water Oxidation at Neutral pH

T Liu, S Zhan, N Shen, L Wang, Z Szabó… - Journal of the …, 2023 - ACS Publications
Many enzymes use adaptive frameworks to preorganize substrates, accommodate various
structural and electronic demands of intermediates, and accelerate related catalysis …

Electrocatalytic water oxidation activity of molecular copper complexes: effect of redox-active ligands

M Bera, K Keshari, A Bhardwaj, G Gupta… - Inorganic …, 2022 - ACS Publications
Two molecular copper (II) complexes,(NMe4) 2 [CuII (L1)](1) and (NMe4) 2 [CuII (L2)](2),
ligated by a N2O2 donor set of ligands [L1= N, N′-(1, 2-phenylene) bis (2-hydroxy-2 …

Strategic factors to design the next generation of molecular water oxidation catalysts: Lesson learned from ruthenium complexes

A Ghaderian, S Kazim, MK Nazeeruddin… - Coordination Chemistry …, 2022 - Elsevier
Energy conversion through sustainable means is essential to counter global warming and
an urgent solution through a multidisciplinary approach is required. The temperature change …

Bifunctional and regenerable molecular electrode for water electrolysis at neutral pH

B Das, EA Toledo-Carrillo, G Li, J Ståhle… - Journal of Materials …, 2023 - pubs.rsc.org
The instability of molecular electrodes under oxidative/reductive conditions and insufficient
understanding of the metal oxide-based systems have slowed down the progress of H2 …

Isolation and identification of pseudo seven-coordinate Ru (III) intermediate completing the catalytic cycle of Ru-bda type of water oxidation catalysts

T Liu, G Li, N Shen, L Wang, BJJ Timmer… - CCS …, 2022 - chinesechemsoc.org
Isolation of RuIII-bda (17-electron specie) complex with an aqua ligand (2-electron donor) is
challenging due to violation of the 18-electron rule. Although considerable efforts have been …