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Earth abundant transition metal complexes as molecular water oxidation catalysts
Coherency of nature has always inspired human to develop, produce and innovate by
imitating it. Photosynthesis is amongst the most efficient bio-chemical reaction nature …
imitating it. Photosynthesis is amongst the most efficient bio-chemical reaction nature …
The impact of ligand carboxylates on electrocatalyzed water oxidation
Conspectus Fossil fuel shortage and severe climate changes due to global warming have
prompted extensive research on carbon-neutral and renewable energy resources …
prompted extensive research on carbon-neutral and renewable energy resources …
A di-copper-peptoid in a noninnocent borate buffer as a fast electrocatalyst for homogeneous water oxidation with low overpotential
Water electrolysis is a promising approach toward low-cost renewable fuels; however, the
high overpotential and slow kinetics limit its applicability. Studies suggest that either …
high overpotential and slow kinetics limit its applicability. Studies suggest that either …
Discovery of PF-07265028, A Selective Small Molecule Inhibitor of Hematopoietic Progenitor Kinase 1 (HPK1) for the Treatment of Cancer
RA Gallego, S Cho-Schultz, M Del Bel… - Journal of Medicinal …, 2024 - ACS Publications
Hematopoietic progenitor kinase 1 (HPK1/MAP4K1) represents a high interest target for the
treatment of cancer through an immune-mediated mechanism. Herein we present highlights …
treatment of cancer through an immune-mediated mechanism. Herein we present highlights …
From Ru-bda to Ru-bds: a step forward to highly efficient molecular water oxidation electrocatalysts under acidic and neutral conditions
Significant advances during the past decades in the design and studies of Ru complexes
with polypyridine ligands have led to the great development of molecular water oxidation …
with polypyridine ligands have led to the great development of molecular water oxidation …
Bioinspired Active Site with a Coordination-Adaptive Organosulfonate Ligand for Catalytic Water Oxidation at Neutral pH
Many enzymes use adaptive frameworks to preorganize substrates, accommodate various
structural and electronic demands of intermediates, and accelerate related catalysis …
structural and electronic demands of intermediates, and accelerate related catalysis …
Electrocatalytic water oxidation activity of molecular copper complexes: effect of redox-active ligands
Two molecular copper (II) complexes,(NMe4) 2 [CuII (L1)](1) and (NMe4) 2 [CuII (L2)](2),
ligated by a N2O2 donor set of ligands [L1= N, N′-(1, 2-phenylene) bis (2-hydroxy-2 …
ligated by a N2O2 donor set of ligands [L1= N, N′-(1, 2-phenylene) bis (2-hydroxy-2 …
Strategic factors to design the next generation of molecular water oxidation catalysts: Lesson learned from ruthenium complexes
Energy conversion through sustainable means is essential to counter global warming and
an urgent solution through a multidisciplinary approach is required. The temperature change …
an urgent solution through a multidisciplinary approach is required. The temperature change …
Bifunctional and regenerable molecular electrode for water electrolysis at neutral pH
The instability of molecular electrodes under oxidative/reductive conditions and insufficient
understanding of the metal oxide-based systems have slowed down the progress of H2 …
understanding of the metal oxide-based systems have slowed down the progress of H2 …
Isolation and identification of pseudo seven-coordinate Ru (III) intermediate completing the catalytic cycle of Ru-bda type of water oxidation catalysts
Isolation of RuIII-bda (17-electron specie) complex with an aqua ligand (2-electron donor) is
challenging due to violation of the 18-electron rule. Although considerable efforts have been …
challenging due to violation of the 18-electron rule. Although considerable efforts have been …