Electrocatalytic nitrate/nitrite reduction to ammonia synthesis using metal nanocatalysts and bio-inspired metalloenzymes

J Wang, T Feng, J Chen, V Ramalingam, Z Li… - Nano Energy, 2021 - Elsevier
Ammonia (NH 3) is attracted as a potential carbon free energy carrier and as important
feedstock for most of the fertilizers, chemicals, pharmaceutical related products. NH 3 is …

Selective reduction of aqueous nitrate to ammonium with an electropolymerized chromium molecular catalyst

MJ Askari, JD Kallick, CCL McCrory - Journal of the American …, 2024 - ACS Publications
Nitrate (NO3–) is a common nitrogen-containing contaminant in agricultural, industrial, and
low-level nuclear wastewater that causes significant environmental damage. In this work, we …

Electrochemical reduction of nitrate on silver surface and an in situ Raman spectroscopy study

F Lei, K Li, M Yang, J Yu, M Xu, Y Zhang… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Electroreduction of nitrates to other essential fertilizers is becoming an important method for
the treatment of nitrate contamination. In this study, Ag nanocrystal catalyst on the quasi …

Supramolecular enhancement of electrochemical nitrate reduction catalyzed by cobalt porphyrin organic cages for ammonia electrosynthesis in water

L An, MR Narouz, PT Smith, P De La Torre… - Angewandte …, 2023 - Wiley Online Library
Abstract The electrochemical nitrate (NO3−) reduction reaction (NO3RR) to ammonia (NH3)
represents a sustainable approach for denitrification to balance global nitrogen cycles and …

Efficient nitrate-to-ammonia electroreduction at cobalt phosphide nanoshuttles

Y Jia, YG Ji, Q Xue, FM Li, GT Zhao, PJ **… - … Applied Materials & …, 2021 - ACS Publications
The nitrate electroreduction reaction (NO3–-ERR) is an efficient and green approach for
nitrate remediation, which requires a highly active and selective electrocatalyst. In this work …

Recent advances in electrocatalytic nitrate reduction: strategies to promote ammonia synthesis

T Ding, M Wang, F Wu, B Song, K Lu… - ACS Applied Energy …, 2024 - ACS Publications
Electrocatalytic nitrate-to-ammonia conversion is a promising and alternative sustainable
approach for replenishing the nitrogen cycle pathway under mild conditions. Develo** …

Computational studies for boosting nitrate electroreduction activity of Fe-N4-C Single-Atom catalyst via axial fifth ligand

Y Huang, C Tang, Q Li, J Gong - Applied Surface Science, 2023 - Elsevier
Single Fe atom coordinated with four planar nitrogen atoms codoped graphene layer (Fe-N
4-C) has emerged as one of the promising single atom electrocatalyst (eSAC) for the …

An integrated view of nitrogen oxyanion deoxygenation in solution chemistry and electrospray ion production

DM Beagan, AC Cabelof, R Pepin, M Pink… - Inorganic …, 2021 - ACS Publications
There has been an increasing interest in chemistry involving nitrogen oxyanions, largely due
to the environmental hazards associated with increased concentrations of these anions …

Electrocatalytic reduction of nitrogen oxyanions with a redox-active cobalt macrocycle complex

S Partovi, Z **ong, KM Kulesa, JM Smith - Inorganic Chemistry, 2022 - ACS Publications
The cobalt complex,[Co (CR) Br2]+, where CR is the redox-active macrocycle 2, 12-dimethyl-
3, 7, 11, 17-tetraazabicyclo-[11.3. 1]-heptadeca-1 (17), 2, 11, 13, 15-pentaene, has been …

Selective Stepwise Reduction of Nitrate and Nitrite to Dinitrogen or Ammonia

JM Moore, TJ Miller, M Mu… - Journal of the …, 2025 - ACS Publications
This study reports a method for the selective reduction of NO3–and NO2–to N2 or NH3,
extending prior work in our lab where NO3–was reduced to NO by [N (afaCy) 3Fe] OTf2 (N …