Mechanochemistry: new tools to navigate the uncharted territory of “impossible” reactions
F Cuccu, L De Luca, F Delogu, E Colacino… - …, 2022 - Wiley Online Library
Mechanochemical transformations have made chemists enter unknown territories, forcing a
different chemistry perspective. While questioning or revisiting familiar concepts belonging …
different chemistry perspective. While questioning or revisiting familiar concepts belonging …
% V Bur index and steric maps: from predictive catalysis to machine learning
Steric indices are parameters used in chemistry to describe the spatial arrangement of
atoms or groups of atoms in molecules. They are important in determining the reactivity …
atoms or groups of atoms in molecules. They are important in determining the reactivity …
Group 16 conjugated polymers based on furan, thiophene, selenophene, and tellurophene
Five-membered aromatic rings containing Group 16 elements (O, S, Se, and Te), also
referred as chalcogenophenes, are ubiquitous building blocks for π-conjugated polymers …
referred as chalcogenophenes, are ubiquitous building blocks for π-conjugated polymers …
Pd (II) and Ni (II) complexes containing ONNO tetradentate Schiff base ligand: Synthesis, crystal structure, spectral characterization, theoretical studies, and use of PdL …
Two new palladium (II) and nickel (II) Schiff base complexes are prepared through the
reaction of Pd (OAc) 2 and Ni (OAc) 2· 4H 2 O with a tetradentate ONNO Schiff base, derived …
reaction of Pd (OAc) 2 and Ni (OAc) 2· 4H 2 O with a tetradentate ONNO Schiff base, derived …
Experimental Evidence for Zerovalent Pd(NHC) as a Competent Catalyst in C–N Cross-Coupling (NHC = DiMeIHeptCl)
V Semeniuchenko, S Sharif, N Rana… - Journal of the …, 2024 - ACS Publications
Use of the branched N-heterocyclic carbene (NHC) ligand 1, 3-bis (2, 6-bis (3-methyl-1-(2-
methylpropyl) butyl) phenyl)-4, 5-dichloro-1, 3-dihydro-2 H-imidazole-2-ylidene …
methylpropyl) butyl) phenyl)-4, 5-dichloro-1, 3-dihydro-2 H-imidazole-2-ylidene …
Pd-functionalized polydopamine-coated polyurethane foam: a readily prepared and highly reusable structured catalyst for selective alkyne semi-hydrogenation and …
H Peng, X Zhang, V Papaefthimiou, C Pham-Huu… - Green …, 2023 - pubs.rsc.org
A polyurethane foam (PUF) was coated with a thin layer of polydopamine (PDA), and Pd
strongly anchored onto PDA via simple immersion of PDA@ PUF in a hydro-alcoholic …
strongly anchored onto PDA via simple immersion of PDA@ PUF in a hydro-alcoholic …
Platinum group metal (PGM) complexes having acylthiourea ligand system as catalysts or anticancer agents
The intention behind the design of a metal complex is quite crucial for its development
towards a particular application. Transition metal complexes have tremendously become …
towards a particular application. Transition metal complexes have tremendously become …
Bioorthogonal nanozymes: an emerging strategy for disease therapy
Z Zhang, K Fan - Nanoscale, 2023 - pubs.rsc.org
Transition metal catalysts (TMCs), capable of performing bioorthogonal reactions, have
been engineered to trigger the formation of bioactive molecules in a controlled manner for …
been engineered to trigger the formation of bioactive molecules in a controlled manner for …
Computational mechanistic study in organometallic catalysis: Why prediction is still a challenge
N Fey, JM Lynam - Wiley Interdisciplinary Reviews …, 2022 - Wiley Online Library
Although computational contributions to the understanding of organometallic homogeneous
catalysts have become fairly routine, a step‐change in the application of computational …
catalysts have become fairly routine, a step‐change in the application of computational …
Preserving surface strain in nanocatalysts via morphology control
Engineering strain critically affects the properties of materials and has extensive applications
in semiconductors and quantum systems. However, the deployment of strain-engineered …
in semiconductors and quantum systems. However, the deployment of strain-engineered …