Progress in the theory of mixed quantum-classical dynamics

R Kapral - Annu. Rev. Phys. Chem., 2006 - annualreviews.org
▪ Abstract Quantum-classical Liouville dynamics can be used to study the properties of open
quantum systems that are coupled to bath or environmental degrees of freedom whose …

Quantum dynamics in open quantum-classical systems

R Kapral - Journal of Physics: Condensed Matter, 2015 - iopscience.iop.org
Often quantum systems are not isolated and interactions with their environments must be
taken into account. In such open quantum systems these environmental interactions can …

Classical description of nonadiabatic quantum dynamics

G Stock, M Thoss - Advances in chemical physics, 2005 - Wiley Online Library
II. Molecular Systems A. Model Hamiltonian B. Observables of Interest C. Model Systems 1.
Model I: S2→ S1 Internal Conversion in Pyrazine 2. Model II: eC→ eB→ eX Internal …

[HTML][HTML] Surface hop**, transition state theory, and decoherence. II. Thermal rate constants and detailed balance

A Jain, JE Subotnik - The Journal of Chemical Physics, 2015 - pubs.aip.org
We investigate a simple approach to compute a non-adiabatic thermal rate constant using
the fewest switches surface hop** (FSSH) dynamics. We study the effects of both …

Ultrafast nonadiabatic dynamics of singlet fission: Quantum dynamics with the multilayer multiconfigurational time-dependent Hartree (ML-MCTDH) method

J Zheng, Y **e, S Jiang, Z Lan - The Journal of Physical Chemistry …, 2016 - ACS Publications
Singlet fission (SF) is supposed to potentially improve the efficiency of solar energy
conversion in organic photovoltaic systems. The multilayer multiconfigurational time …

A Quantum–Classical Model of Brain Dynamics

A Sergi, A Messina, CM Vicario, G Martino - Entropy, 2023 - mdpi.com
The study of the human psyche has elucidated a bipartite structure of logic reflecting the
quantum–classical nature of the world. Accordingly, we posited an approach toward …

Quantum-classical Liouville dynamics of nonadiabatic proton transfer

G Hanna, R Kapral - The Journal of chemical physics, 2005 - pubs.aip.org
A proton transfer reaction in a linear hydrogen-bonded complex dissolved in a polar solvent
is studied using mixed quantum-classical Liouville dynamics. In this system, the proton is …

[HTML][HTML] On simulating the dynamics of electronic populations and coherences via quantum master equations based on treating off-diagonal electronic coupling terms …

Y Lai, E Geva - The Journal of Chemical Physics, 2021 - pubs.aip.org
Quantum master equations provide a general framework for describing the dynamics of
electronic observables within a complex molecular system. One particular family of such …

Simulating quantum dynamics in classical environments

A Sergi, DM Kernan, G Ciccotti, R Kapral - Theoretical Chemistry Accounts, 2003 - Springer
Methods for simulating the dynamics of composite systems, where part of the system is
treated quantum mechanically and its environment is treated classically, are discussed …

Quasi-Lie brackets and the breaking of time-translation symmetry for quantum systems embedded in classical baths

A Sergi, G Hanna, R Grimaudo, A Messina - Symmetry, 2018 - mdpi.com
Many open quantum systems encountered in both natural and synthetic situations are
embedded in classical-like baths. Often, the bath degrees of freedom may be represented in …