Designing catalysts for olefin polymerization and copolymerization: beyond electronic and steric tuning

C Chen - Nature Reviews Chemistry, 2018 - nature.com
More than 50 years have passed since Ziegler and Natta shared the Nobel Prize in
Chemistry for their discovery of olefin polymerization catalysts. The field of metal-catalysed …

Ultrahigh molecular weight polyethylene: Catalysis, structure, properties, processing and applications

K Patel, SH Chikkali, S Sivaram - Progress in polymer science, 2020 - Elsevier
Ultrahigh molecular weight polyethylene (UHMWPE) belongs to an emerging class of high-
performance specialty polymers with a unique set of properties and applications. The field …

From multisite polymerization catalysis to sustainable materials and all-polyolefin composites

M Stürzel, S Mihan, R Mülhaupt - Chemical reviews, 2016 - ACS Publications
Since the pioneering advances of Karl Ziegler and Giulio Natta during the early 1950s, a
continuing series of breakthroughs in research and industrial innovations have greatly …

Post‐metallocenes in the industrial production of polyolefins

MC Baier, MA Zuideveld… - Angewandte Chemie …, 2014 - Wiley Online Library
Research on “post‐metallocene” polymerization catalysis ranges methodologically from
fundamental mechanistic studies of polymerization reactions over catalyst design to material …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Polyolefins, a success story

DW Sauter, M Taoufik, C Boisson - Polymers, 2017 - mdpi.com
This paper reports the principal discoveries which have played a major role in the polyolefin
field and have positioned polyolefins as the most produced plastics. The early development …

Coordination− insertion copolymerization of fundamental polar monomers

A Nakamura, S Ito, K Nozaki - Chemical reviews, 2009 - ACS Publications
Akifumi Nakamura (left) was born in 1984 in Kanagawa, Japan. He received his BS degree
in 2007 and MS degree in 2009 from the University of Tokyo under the guidance of …

Multinuclear olefin polymerization catalysts

M Delferro, TJ Marks - Chemical reviews, 2011 - ACS Publications
1.1. Inspired by Nature In many enzymes, such as ureases (Figure 1), two or more metal
centers are poised in close proximity to activate both electrophilic and nucleophilic …

Recent advancements in α-diimine-nickel and-palladium catalysts for ethylene polymerization

M Qasim, MS Bashir, S Iqbal, Q Mahmood - European Polymer Journal, 2021 - Elsevier
The fascination of the well-defined metal catalysts for olefin polymerization is their capability
to control the properties of the polymer such as topology (linear to highly branched), range of …

Multinuclear group 4 catalysis: Olefin polymerization pathways modified by strong metal–metal cooperative effects

JP McInnis, M Delferro, TJ Marks - Accounts of chemical research, 2014 - ACS Publications
Conspectus Polyolefins are produced today catalytically on a vast scale, and the
manufactured polymers find use in everything from artificial limbs and food/medical …