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Electroreductive cross‐electrophile coupling (eXEC) reactions
Y Liu, P Li, Y Wang, Y Qiu - Angewandte Chemie, 2023 - Wiley Online Library
Electrochemistry utilizes electrons as a potent, controllable, and traceless alternative to
chemical oxidants or reductants, and typically offers a more sustainable option for achieving …
chemical oxidants or reductants, and typically offers a more sustainable option for achieving …
Pd-catalyzed cross-couplings: On the importance of the catalyst quantity descriptors, mol% and ppm
CS Horbaczewskyj, IJS Fairlamb - Organic Process Research & …, 2022 - ACS Publications
This Review examines parts per million (ppm) palladium concentrations in catalytic cross-
coupling reactions and their relationship with mole percentage (mol%). Most studies in …
coupling reactions and their relationship with mole percentage (mol%). Most studies in …
Electrochemical NiH‐Catalyzed C(sp3)−C(sp3) Coupling of Alkyl Halides and Alkyl Alkenes
P Li, G Kou, T Feng, M Wang, Y Qiu - Angewandte Chemie, 2023 - Wiley Online Library
Herein, an electrochemically driven NiH‐catalyzed reductive coupling of alkyl halides and
alkyl alkenes for the construction of Csp3− Csp3 bonds is firstly reported. Notably, alkyl …
alkyl alkenes for the construction of Csp3− Csp3 bonds is firstly reported. Notably, alkyl …
In-situ bromination enables formal cross-electrophile coupling of alcohols with aryl and alkenyl halides
BK Chi, JK Widness, MM Gilbert, DC Salgueiro… - ACS …, 2021 - ACS Publications
Although alcohols are one of the largest pools of alkyl substrates, approaches to utilize them
in cross-coupling and cross-electrophile coupling are limited. We report the use of 1° and 2° …
in cross-coupling and cross-electrophile coupling are limited. We report the use of 1° and 2° …
Recent trends in the chemistry of Sandmeyer reaction: a review
Metal-catalyzed reactions play a vital part to construct a variety of pharmaceutically
important scaffolds from past few decades. To carry out these reactions under mild …
important scaffolds from past few decades. To carry out these reactions under mild …
Ni-Catalyzed Deoxygenative Cross-Coupling of Alcohols with Aryl Chlorides via an Organic Photoredox Process
W **ong, T Kang, F Li, H Liao, Y Yan, J Dong, G Li… - ACS …, 2024 - ACS Publications
Cross-electrophile coupling from naturally abundant materials is of significant value in
organic synthesis. Herein, we established a highly efficient deoxygenative cross-coupling …
organic synthesis. Herein, we established a highly efficient deoxygenative cross-coupling …
A Comprehensive Review on Benzofuran Synthesis Featuring Innovative and Catalytic Strategies
Benzofurans have intrigued both pharmaceutical researchers and chemists owing to the
medicinal usage of their derivatives against copious disease-causing agents (ie, bacteria …
medicinal usage of their derivatives against copious disease-causing agents (ie, bacteria …
Update on novel synthetic approaches towards the construction of carbazole nuclei: a review
The carbazole scaffold is a significant entity in organic compounds due to its variety of
biological and synthetic applications. Traditionally, carbazole skeletons have been …
biological and synthetic applications. Traditionally, carbazole skeletons have been …
Recent green synthetic approaches toward Ullmann reaction: A review
The traditional Ullmann reaction which represents the copper-catalyzed coupling between
two aryl halides to build a C–C bond was first reported in 1901. Over the time, this reaction …
two aryl halides to build a C–C bond was first reported in 1901. Over the time, this reaction …
Cloke–Wilson rearrangement: a unique gateway to access five-membered heterocycles
Cyclopropanes are of great synthetic value in heterocyclic chemistry due to their highly
reactive nature. They are widely employed to synthesize various biologically active organic …
reactive nature. They are widely employed to synthesize various biologically active organic …