Electroreductive Cross‐Electrophile Coupling (eXEC) Reactions

Y Liu, P Li, Y Wang, Y Qiu - Angewandte Chemie, 2023 - Wiley Online Library
Electrochemistry utilizes electrons as a potent, controllable, and traceless alternative to
chemical oxidants or reductants, and typically offers a more sustainable option for achieving …

Pd-catalyzed cross-couplings: On the importance of the catalyst quantity descriptors, mol% and ppm

CS Horbaczewskyj, IJS Fairlamb - Organic Process Research & …, 2022 - ACS Publications
This Review examines parts per million (ppm) palladium concentrations in catalytic cross-
coupling reactions and their relationship with mole percentage (mol%). Most studies in …

Electrochemical NiH‐Catalyzed C(sp3)−C(sp3) Coupling of Alkyl Halides and Alkyl Alkenes

P Li, G Kou, T Feng, M Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
Herein, an electrochemically driven NiH‐catalyzed reductive coupling of alkyl halides and
alkyl alkenes for the construction of Csp3− Csp3 bonds is firstly reported. Notably, alkyl …

In-situ bromination enables formal cross-electrophile coupling of alcohols with aryl and alkenyl halides

BK Chi, JK Widness, MM Gilbert, DC Salgueiro… - ACS …, 2021 - ACS Publications
Although alcohols are one of the largest pools of alkyl substrates, approaches to utilize them
in cross-coupling and cross-electrophile coupling are limited. We report the use of 1° and 2° …

Recent trends in the chemistry of Sandmeyer reaction: a review

R Akhtar, AF Zahoor, N Rasool, M Ahmad, KG Ali - Molecular Diversity, 2022 - Springer
Metal-catalyzed reactions play a vital part to construct a variety of pharmaceutically
important scaffolds from past few decades. To carry out these reactions under mild …

Ni-Catalyzed Deoxygenative Cross-Coupling of Alcohols with Aryl Chlorides via an Organic Photoredox Process

W **ong, T Kang, F Li, H Liao, Y Yan, J Dong, G Li… - ACS …, 2024 - ACS Publications
Cross-electrophile coupling from naturally abundant materials is of significant value in
organic synthesis. Herein, we established a highly efficient deoxygenative cross-coupling …

Cloke–Wilson rearrangement: a unique gateway to access five-membered heterocycles

U Nazeer, A Mushtaq, AF Zahoor, F Hafeez… - RSC …, 2023 - pubs.rsc.org
Cyclopropanes are of great synthetic value in heterocyclic chemistry due to their highly
reactive nature. They are widely employed to synthesize various biologically active organic …

Chitosan-Pd0 nanoparticles encapsulated in Al, Co-pillared montmorillonite by one-pot process

K Sun, T Zhang, J Zhou, Y Liu, M Zeng, Z Yang… - Applied Clay …, 2024 - Elsevier
Abstract Chitosan-Pd 0 (CS-Pd 0) nano particles encapsulated in Al, Co-pillared
montmorillonite (MMt) nanocomposites were synthesized by a facile one-pot heat treatment …

Recent green synthetic approaches toward Ullmann reaction: A review

R Akhtar, AF Zahoor, M Irfan, TH Bokhari, A ul Haq - Chemical Papers, 2022 - Springer
The traditional Ullmann reaction which represents the copper-catalyzed coupling between
two aryl halides to build a C–C bond was first reported in 1901. Over the time, this reaction …

Design, Synthesis, and Biological Activity Evaluation of Novel AZT and Adenosine‐Derived 1, 2, 3‐Triazoles

DA Le, NH Truong, VD Vu, TH Doan, MT Le… - Journal of …, 2023 - Wiley Online Library
CuSO4/hydrazine hydrate was used as a catalyst system for copper (I)‐catalyzed alkyne‐
azide cycloaddition (CuAAC) of AZT and 5′‐azido adenosine with terminal alkynes to give …