Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Construction of covalent organic frameworks via multicomponent reactions

Q Guan, LL Zhou, YB Dong - Journal of the American Chemical …, 2023 - ACS Publications
Multicomponent reactions (MCRs) combine at least three reactants to afford the desired
product in a highly atom-economic way and are therefore viewed as efficient one-pot …

Strain enhances the activity of molecular electrocatalysts via carbon nanotube supports

J Su, CB Musgrave III, Y Song, L Huang, Y Liu, G Li… - Nature Catalysis, 2023 - nature.com
Support-induced strain engineering is useful for modulating the properties of two-
dimensional materials. However, controlling strain of planar molecules is technically …

Post-synthetic modification of covalent organic frameworks for CO2 electroreduction

M Liu, S Yang, X Yang, CX Cui, G Liu, X Li, J He… - Nature …, 2023 - nature.com
To achieve high-efficiency catalysts for CO2 reduction reaction, various catalytic metal
centres and linker molecules have been assembled into covalent organic frameworks. The …

Direct synthesis of ammonia from nitrate on amorphous graphene with near 100% efficiency

L Huang, L Cheng, T Ma, JJ Zhang, H Wu… - Advanced …, 2023 - Wiley Online Library
Ammonia is an indispensable commodity in the agricultural and pharmaceutical industries.
Direct nitrate‐to‐ammonia electroreduction is a decentralized route yet challenged by …

Accelerating multielectron reduction at CuxO nanograins interfaces with controlled local electric field

W Guo, S Zhang, J Zhang, H Wu, Y Ma, Y Song… - Nature …, 2023 - nature.com
Regulating electron transport rate and ion concentrations in the local microenvironment of
active site can overcome the slow kinetics and unfavorable thermodynamics of CO2 …

Modulating skeletons of covalent organic framework for high‐efficiency gold recovery

M Liu, D Jiang, Y Fu, G Zheng Chen, S Bi… - Angewandte …, 2024 - Wiley Online Library
Covalent organic frameworks (COFs) have attracted considerable attention as adsorbents
for capturing and separating gold from electronic wastes. To enhance the binding capture …

Ultrathin, Cationic Covalent Organic Nanosheets for Enhanced CO2 Electroreduction to Methanol

Y Song, P Guo, T Ma, J Su, L Huang, W Guo… - Advanced …, 2024 - Wiley Online Library
Metalloporphyrins and metallophthalocyanines emerge as popular building blocks to
develop covalent organic nanosheets (CONs) for CO2 reduction reaction (CO2RR) …

Value‐Added Cascade Synthesis Mediated by Paired‐Electrolysis Using an Ultrathin Microenvironment‐Inbuilt Metalized Covalent Organic Framework …

Q Li, DD Ma, WB Wei, SG Han… - Advanced Energy …, 2024 - Wiley Online Library
Energy‐saving and value‐added management in advanced catalysis is highly desirable but
is challenged by the limitations of multifunctional catalysts and catalytic modules. Herein, an …

Efficient Electrocatalytic Reduction of CO2 to Ethanol Enhanced by Spacing Effect of CuCu in Cu2‐xSe Nanosheets

H Wang, X Bi, Y Yan, Y Zhao, Z Yang… - Advanced Functional …, 2023 - Wiley Online Library
It is highly desired yet challenging to strategically steer carbon dioxide (CO2)
electroreduction reaction (CO2ER) toward ethanol (EtOH) with high activity, which provides …