Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Liquid metals: fundamentals and applications in chemistry

T Daeneke, K Khoshmanesh, N Mahmood… - Chemical Society …, 2018 - pubs.rsc.org
Post-transition elements, together with zinc-group metals and their alloys belong to an
emerging class of materials with fascinating characteristics originating from their …

Topological quantum materials for energy conversion and storage

H Luo, P Yu, G Li, K Yan - Nature Reviews Physics, 2022 - nature.com
Topological quantum materials (TQMs) have symmetry-protected band structures with useful
electronic properties that have applications in information, sensing, energy and other …

Single-atom Pt in intermetallics as an ultrastable and selective catalyst for propane dehydrogenation

Y Nakaya, J Hirayama, S Yamazoe, K Shimizu… - Nature …, 2020 - nature.com
Propylene production via propane dehydrogenation (PDH) requires high reaction
temperatures to obtain sufficient propylene yields, which results to prominent catalyst …

PdZn intermetallic nanostructure with Pd–Zn–Pd ensembles for highly active and chemoselective semi-hydrogenation of acetylene

H Zhou, X Yang, L Li, X Liu, Y Huang, X Pan… - Acs …, 2016 - ACS Publications
Intermetallic alloying of one active metal to another inert metal provides not only the
improved dispersion of active centers but also a unique and homogeneous ensemble of …

Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation

S Zou, B Lou, K Yang, W Yuan, C Zhu, Y Zhu… - Nature …, 2021 - nature.com
Metal/oxide interface is of fundamental significance to heterogeneous catalysis because the
seemingly “inert” oxide support can modulate the morphology, atomic and electronic …

Surface chemistry of gallium-based liquid metals

Y Ding, M Zeng, L Fu - Matter, 2020 - cell.com
The surface of liquid metals plays a critical role in establishing thermodynamic equilibria
(both mass and energy) at the interface between liquid metal and air. The exploration on the …

Aluminum nanocrystals as a plasmonic photocatalyst for hydrogen dissociation

L Zhou, C Zhang, MJ McClain, A Manjavacas… - Nano …, 2016 - ACS Publications
Hydrogen dissociation is a critical step in many hydrogenation reactions central to industrial
chemical production and pollutant removal. This step typically utilizes the favorable band …

Gallium-rich Pd–Ga phases as supported liquid metal catalysts

N Taccardi, M Grabau, J Debuschewitz, M Distaso… - Nature …, 2017 - nature.com
A strategy to develop improved catalysts is to create systems that merge the advantages of
heterogeneous and molecular catalysis. One such system involves supported liquid-phase …