Best‐practice DFT protocols for basic molecular computational chemistry

M Bursch, JM Mewes, A Hansen… - Angewandte Chemie …, 2022 - Wiley Online Library
Nowadays, many chemical investigations are supported by routine calculations of molecular
structures, reaction energies, barrier heights, and spectroscopic properties. The lion's share …

[HTML][HTML] TURBOMOLE: Modular program suite for ab initio quantum-chemical and condensed-matter simulations

SG Balasubramani, GP Chen, S Coriani… - The Journal of …, 2020 - pubs.aip.org
TURBOMOLE is a collaborative, multi-national software development project aiming to
provide highly efficient and stable computational tools for quantum chemical simulations of …

Exploring Coordination of Neodymium in Ionic Liquid: Insights to Guide Sustainable Recovery

GS Dobhal, LN Pham, SA Tawfik… - ACS Sustainable …, 2023 - ACS Publications
Neodymium is a critical metal essential for advancing sustainable clean energy
technologies, as it is a crucial component in the manufacturing of NdFeB permanent …

Late-stage diversification of indole skeletons through nitrogen atom insertion

JC Reisenbauer, O Green, A Franchino, P Finkelstein… - Science, 2022 - science.org
Compared with peripheral late-stage transformations mainly focusing on carbon–hydrogen
functionalizations, reliable strategies to directly edit the core skeleton of pharmaceutical lead …

Orbital-free density functional theory: An attractive electronic structure method for large-scale first-principles simulations

W Mi, K Luo, SB Trickey, M Pavanello - Chemical Reviews, 2023 - ACS Publications
Kohn–Sham Density Functional Theory (KSDFT) is the most widely used electronic structure
method in chemistry, physics, and materials science, with thousands of calculations cited …

Carbene-stabilized enantiopure heterometallic clusters featuring EQE of 20.8% in circularly-polarized OLED

XH Ma, J Li, P Luo, JH Hu, Z Han, XY Dong… - Nature …, 2023 - nature.com
Bright and efficient chiral coinage metal clusters show promise for use in emerging circularly
polarized light-emitting materials and diodes. To date, highly efficient circularly polarized …

Single platinum atoms immobilized on an MXene as an efficient catalyst for the hydrogen evolution reaction

J Zhang, Y Zhao, X Guo, C Chen, CL Dong, RS Liu… - Nature Catalysis, 2018 - nature.com
Single-atom catalysts offer a pathway to cost-efficient catalysis using the minimal amount of
precious metals. However, preparing and kee** them stable during operation remains a …

A generally applicable atomic-charge dependent London dispersion correction

E Caldeweyher, S Ehlert, A Hansen… - The Journal of …, 2019 - pubs.aip.org
The so-called D4 model is presented for the accurate computation of London dispersion
interactions in density functional theory approximations (DFT-D4) and generally for atomistic …

Thirty years of density functional theory in computational chemistry: an overview and extensive assessment of 200 density functionals

N Mardirossian, M Head-Gordon - Molecular physics, 2017 - Taylor & Francis
In the past 30 years, Kohn–Sham density functional theory has emerged as the most popular
electronic structure method in computational chemistry. To assess the ever-increasing …

Photoinduced inverse vulcanization

J Jia, J Liu, ZQ Wang, T Liu, P Yan, XQ Gong… - Nature Chemistry, 2022 - nature.com
The inverse vulcanization (IV) of elemental sulfur to generate sulfur-rich functional polymers
has attracted much recent attention. However, the harsh reaction conditions required, even …