Intrinsically self-healing polymers: from mechanistic insight to current challenges

B Li, PF Cao, T Saito, AP Sokolov - Chemical Reviews, 2022 - ACS Publications
Self-healing materials open new prospects for more sustainable technologies with improved
material performance and devices' longevity. We present an overview of the recent …

Dynamic covalent polymer networks: a molecular platform for designing functions beyond chemical recycling and self-healing

N Zheng, Y Xu, Q Zhao, T **e - Chemical Reviews, 2021 - ACS Publications
Dynamic covalent polymer networks (DCPN) have historically attracted attention for their
unique roles in chemical recycling and self-healing, which are both relevant for sustainable …

Hydrogels and hydrogel-derived materials for energy and water sustainability

Y Guo, J Bae, Z Fang, P Li, F Zhao, G Yu - Chemical reviews, 2020 - ACS Publications
Energy and water are of fundamental importance for our modern society, and advanced
technologies on sustainable energy storage and conversion as well as water resource …

Recyclable and malleable thermosets enabled by activating dormant dynamic linkages

Z Lei, H Chen, C Luo, Y Rong, Y Hu, Y **, R Long… - Nature Chemistry, 2022 - nature.com
Chemical recycling of polymers is critical for improving the circular economy of plastics and
environmental sustainability. Traditional thermoset polymers have generally been …

Self-healing polymers

S Wang, MW Urban - Nature Reviews Materials, 2020 - nature.com
Self-healing is the capability of a material to recover from physical damage. Both physical
and chemical approaches have been used to construct self-healing polymers. These include …

Elastic vitrimers: Beyond thermoplastic and thermoset elastomers

J Luo, Z Demchuk, X Zhao, T Saito, M Tian, AP Sokolov… - Matter, 2022 - cell.com
Thermoset elastomers are widely used in industry and frontier research due to their
advantage of mechanical robustness, high thermal/chemical resistance, and good …

A review on self-healing polymers for soft robotics

S Terryn, J Langenbach, E Roels, J Brancart… - Materials Today, 2021 - Elsevier
The intrinsic compliance of soft robots provides safety, a natural adaptation to its
environment, allows to absorb shocks, and protects them against mechanical impacts …

Adaptable crosslinks in polymeric materials: resolving the intersection of thermoplastics and thermosets

GM Scheutz, JJ Lessard, MB Sims… - Journal of the American …, 2019 - ACS Publications
The classical division of polymeric materials into thermoplastics and thermosets based on
covalent network structure often implies that these categories are distinct and irreconcilable …

Evolution of self-healing elastomers, from extrinsic to combined intrinsic mechanisms: A review

S Utrera-Barrios, R Verdejo, MA López-Manchado… - Materials …, 2020 - pubs.rsc.org
The evolution of self-healing polymers has resulted in a myriad of healing designs that have
given way to complex systems capable of supporting multiple cycles, among other features …

Recent progress in self-healing polymers and hydrogels based on reversible dynamic B–O bonds: boronic/boronate esters, borax, and benzoxaborole

S Cho, SY Hwang, DX Oh, J Park - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
Intrinsic self-healing polymeric materials are substances that relieve external stress and
restore their original mechanical properties after extreme damage via dynamic covalent …