This review is focused on a special class of metal complexes where polyhalide units are
either coordinated to metal (“true polyhalide complexes”) or form specific associates with …

The axial and equatorial bulkiness in the α-diimine Ni/Pd type complexes are two crucial
parameters that govern the catalytic activity, the thermostability of precatalysts and the …

Reactions of the alkyl isocyanide fac-[Tc (CO) 3 (CNR) 2Cl] complexes (2)(CNR= CN n Bu or
CN t Bu) with the sterically encumbered isocyanide CN p-FArDarF2 [DArF= 3, 5-(CF3) …

To assess the relative electronic influence of highly substituted aryl isocyanides on transition
metal centers, a series of C 4 v-symmetric Cr (CNR)(CO) 5 complexes featuring various …

Reaction of [(XA2) U (CH2SiMe3) 2](1; XA2= 4, 5-bis (2, 6-diisopropylanilido)-2, 7-di-tert-
butyl-9, 9-dimethylxanthene) with 1 equivalent of [Ph3C][B (C6F5) 4] in arene solvents …

Transition metal complexes that contain metal-to-ligand retrodative σ-bonds have become
the subject of increasing studies over the last decade. Lewis acidic “Z-type ligands” can …

In the present work, we have prepared nickel phenoxyimine-polyethylene glycol (PEG)
catalysts with sterically bulky N-aryl substituents and investigated their ethylene homo-and …

Organometallic approaches are of ongoing interest for the development of novel functional
99mTc radiopharmaceuticals, while the basic organotechnetium chemistry seems frequently …

Reported here are synthetic studies probing highly reduced iron centers in an encumbering
tetraisocyano ligand environment. Treatment of FeCl2 with sodium amalgam in the presence …

A series of technetium complexes with the sterically encumbered m-terphenyl isocyanides
CNArDipp2 (Dipp= 2, 6-diisopropylphenyl) and CNArMes2 (Mes= 2, 4, 6-trimethylphenyl) …