The mechanochemical synthesis of polymers

A Krusenbaum, S Grätz, GT Tigineh… - Chemical Society …, 2022 - pubs.rsc.org
Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …

Externally controlled atom transfer radical polymerization

X Pan, M Fantin, F Yuan, K Matyjaszewski - Chemical Society Reviews, 2018 - pubs.rsc.org
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …

Atom transfer radical polymerization: billion times more active catalysts and new initiation systems

TG Ribelli, F Lorandi, M Fantin… - Macromolecular rapid …, 2019 - Wiley Online Library
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

Role of external field in polymerization: mechanism and kinetics

YN Zhou, JJ Li, YY Wu, ZH Luo - Chemical reviews, 2020 - ACS Publications
The past decades have witnessed an increasing interest in develo** advanced
polymerization techniques subjected to external fields. Various physical modulations, such …

Electrochemically mediated atom transfer radical polymerization (eATRP)

P Chmielarz, M Fantin, S Park, AA Isse… - Progress in Polymer …, 2017 - Elsevier
This review covers both fundamental aspects and applications of electrochemically
mediated atom transfer radical polymerization (eATRP). eATRP setup is discussed in detail …

Kinetics of atom transfer radical polymerization

P Krys, K Matyjaszewski - European Polymer Journal, 2017 - Elsevier
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …

Preparation of biomolecule-polymer conjugates by grafting-from using ATRP, RAFT, or ROMP

MS Messina, KMM Messina, A Bhattacharya… - Progress in polymer …, 2020 - Elsevier
Biomolecule-polymer conjugates are constructs that take advantage of the functional or
otherwise beneficial traits inherent to biomolecules and combine them with synthetic …

[HTML][HTML] Progress in ATRP-derived materials for biomedical applications

MK Yazdi, P Zarrintaj, MR Saeb, M Mozafari… - Progress in Materials …, 2024 - Elsevier
The continuing wave of technological breakthroughs and advances is critical for engineering
well-defined materials, particularly biomaterials, with tailored microstructure and properties …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

Photocontrolled living polymerization systems with reversible deactivations through electron and energy transfer

S Shanmugam, J Xu, C Boyer - Macromolecular Rapid …, 2017 - Wiley Online Library
Recently, visible‐light‐regulated polymerization has been gaining popularity, as it opens a
range of new opportunities for the synthesis of functional polymers and materials. Here, the …