Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Design and synthesis of noble metal‐based alloy electrocatalysts and their application in hydrogen evolution reaction

Z Cui, W Jiao, ZY Huang, G Chen, B Zhang, Y Han… - Small, 2023 - Wiley Online Library
Hydrogen energy is regarded as the ultimate energy source for future human society, and
the preparation of hydrogen from water electrolysis is recognized as the most ideal way. One …

Probing the atomically diffuse interfaces in Pd@ Pt core-shell nanoparticles in three dimensions

Z Li, Z **e, Y Zhang, X Mu, J **e, HJ Yin… - Nature …, 2023 - nature.com
Deciphering the three-dimensional atomic structure of solid-solid interfaces in core-shell
nanomaterials is the key to understand their catalytical, optical and electronic properties …

Recent development of noble metal-based bimetallic nanoparticles for colorimetric sensing

X Liu, X Liang, J Yu, K Xu, JW Shen, W Duan… - TrAC Trends in Analytical …, 2023 - Elsevier
Colorimetric sensors with instant visual readout are significant and highly required for
convenient detection of various analytes, especially in the post-COVID-19 era. Noble metal …

Engineering ultra-strong electron-phonon coupling and nonclassical electron transport in crystalline gold with nanoscale interfaces

S Kumbhakar, TK Maji, B Tongbram, S Mandal… - Nature …, 2025 - nature.com
Electrical resistivity in good metals, particularly noble metals such as gold (Au), silver (Ag),
or copper, increases linearly with temperature (T) for T> Θ D, where Θ D is the Debye …

Liquid Metal Nanoreactor Enables Living Galvanic Replacement Reaction

T Gan, W Shang, S Handschuh-Wang… - Chemistry of …, 2024 - ACS Publications
Galvanic replacement reaction (GRR) holds immense potential for engineering metal
nanostructures. This reaction allows for the formation of bimetallic hollow nanostructures in a …

Preparation of Ni@Pd Core–Shell Nanoparticles Supported on KIT-6 by Ultrasound-Assisted Galvanic Replacement for Dodecahydro-N-ethylcarbazole …

Z Feng, Z Liu, X Bai - Inorganic Chemistry, 2023 - ACS Publications
Using Ni as a template and reductant, Ni core–Pd shell nanoparticles (Ni@ Pd NPs)
supported on KIT-6 (Ni@ Pd/K6) were prepared by a galvanic replacement reaction under …

Glutathione-Mediated Synthesis of Yolk–Shell AuAg Nanostructures Containing a Spherical Core and Cuboctahedral Skeletons and Their Applications in Plasmonic …

X Li, Y Min, F Liu, M Liu, Y Zheng - Langmuir, 2023 - ACS Publications
Frame/skeleton-like nanostructures are of great value in plasmonic catalysis as a result of
the synergetic structural advantages arising from both maximized surface atomic exposure …

Decoupling Intrinsic Metal Ion Reduction Rates from Structural Outcomes in Multimetallic Nanoparticles

JH Smith, Q Luo, SL Millheim… - Journal of the American …, 2024 - ACS Publications
Simultaneously controlling both stoichiometry and atom arrangement during the synthesis of
multimetallic nanoparticles is often challenging, especially when the desired metal …

Cryogels with Noble metal nanoparticles as catalyst for “green” decomposition of Chlorophenols

DA Berillo, IN Savina - Inorganics, 2023 - mdpi.com
Pollution of the aquatic environment by halogen derivatives widely used as antiseptic
compounds, as well as chemicals for various industrial purposes, is significant. Existing …