Over the past few decades, there have been major developments in transition metal-
catalyzed asymmetric cyclization reactions, enabling the convenient access to a wide …

Oxazoline-containing ligands have been widely employed in numerous asymmetric catalytic
reactions. Pyridine-oxazoline-type ligands, a class of hybrid ligands, were designed earlier …

The arylethylamine pharmacophore is conserved across a range of biologically active
natural products and pharmaceuticals, particularly in molecules that act on the central …

Two-or one-electron-mediated difunctionalizations of internal alkenes represent
straightforward approaches to assemble molecular complexity by the simultaneous …

An intermolecular, two‐component vicinal carboimination of alkenes has been
accomplished by energy transfer catalysis. Oxime esters of alkyl carboxylic acids were used …

The asymmetric synthesis of alkynyl and monofluoroalkenyl isoindolinones from N‐methoxy
benzamides and α, α‐difluoromethylene alkynes is enabled by C− H activation with a chiral …

A nickel‐catalyzed asymmetric reductive Heck reaction of aryl chlorides has been
developed that affords substituted indolines with high enantioselectivity. Manganese powder …

Intermolecular carboamination of olefins with general alkyl groups is an unsolved problem.
Diastereoselective carboamination of acyclic olefins represents an additional challenge in …

A photoredox-catalyzed 1, 2-amidoheteroarylation of unactivated alkenes with O-acyl
hydroxylamine derivatives and heterocycles is presented. A range of heterocycles, including …

In the present work, an asymmetric copper‐catalyzed radical multi‐component cascade
reaction of an unsaturated carboxylic acid, aryldiazonium tetrafluoroborate, and …