Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

The development of molecular materials with novel functionality offers promise for
technological innovation. Switchable molecules that incorporate redox‐active components …

Redox isomerism, which is a reversible metal-to-ligand electron transfer, was first reported
by Pierpont and Buchanan in 1980 for an o-benzoquinone complex of cobalt.[1] A few years …

The 4f orbitals of Ce (IV) have shown appreciably enhanced covalent mixing with ligand
orbitals relative to those of Ce (III). Here, X-ray spectroscopy, magnetic susceptibility …

The synthesis, structure, and reactivity of a uranium metallacyclopropene were
comprehensively studied. Reduction of (η5-C5Me5) 2UCl2 (1) with potassium graphite …

The uranium bipyridyl metallocene,[η5-1, 3-(Me3Si) 2C5H3] 2U (bipy)(2), is readily
accessible in good yield by adding potassium graphite (KC8) to a mixture of [η5-1, 3-(Me3Si) …

The reduction of [η5-1, 2, 4-(Me3C) 3C5H2] 2ThCl2 (1) with potassium graphite in the
presence of 2, 2′-bipyridine gives the purple thorium bipy metallocene [η5-1, 2, 4-(Me3C) …

Previous magnetic, spectroscopic, and theoretical studies of cerocene, Ce (C8H8) 2, have
provided evidence for non-negligible 4f-electron density on Ce and implied that charge …

Photophysical and magnetic properties arising from both ground and excited states of
lanthanoid ions are relevant for numerous applications. These properties can be …

At the dawn of the development of structural organometallic chemistry, soon after the
discovery of ferrocene, the description of the LnCp3 complexes, featuring large and mostly …