Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …

The concept of strain in organic compounds is as old as modern organic chemistry and was
initially introduced to justify the synthetic setbacks along the synthesis of small ring systems …

Dearomative photocycloadditions are valuable chemical transformations, serving as an
efficient platform to create three-dimensional molecular complexity. However, the …

Synthesis of bicyclic scaffolds has attracted growing interest because they are of high
importance in modern pharmaceutical development. Here we report a strategy to access …

Conspectus Exploring the enormous chemical space through an expedient building-up of
molecular diversity is an important goal of organic chemistry. The development of synthetic …

Dearomative photocycloaddition of monocyclic arenes is an appealing strategy for
comprehending the concept of “escape from flatland”. This brings the replacement of readily …

Photocycloaddition is a powerful reaction to enable the conversion of alkenes into high-
value synthetic materials that are normally difficult to obtain under thermal conditions …

Dearomatization reactions have become fundamental chemical transformations in organic
synthesis since they allow for the generation of three-dimensional complexity from two …

Photochemical dearomative cycloaddition has emerged as a useful strategy to rapidly
generate molecular complexity. Within this context, stereo-and regiocontrolled …

Utilization of oxime esters as bifunctional reagents in energy-transfer photocatalysis has
received considerable attention. However, the reaction type is so far limited to the …