Methodologies and strategies for selective borylation of C–Het and C–C bonds

M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Diboron (4) compounds: from structural curiosity to synthetic workhorse

EC Neeve, SJ Geier, IAI Mkhalid, SA Westcott… - Chemical …, 2016 - ACS Publications
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides

SK Parida, T Mandal, S Das, SK Hota, S De Sarkar… - ACS …, 2021 - ACS Publications
The past decade has witnessed the emergence of N-(acyloxy) phthalimides (NHPI esters)
and its derivatives at the forefront of synthetic methods facilitating the construction of diverse …

Diboron (4)‐catalyzed remote [3+ 2] cycloaddition of cyclopropanes via dearomative/rearomative radical transmission through pyridine

M Xu, Z Wang, Z Sun, Y Ouyang, Z Ding… - Angewandte …, 2022 - Wiley Online Library
Ring structures such as pyridine, cyclopentane or their combinations are important motifs in
bioactive molecules. In contrast to previous cycloaddition reactions that necessitated a …

Recent advances in the synthesis of difluorinated architectures from trifluoromethyl groups

F Zhao, W Zhou, Z Zuo - Advanced Synthesis & Catalysis, 2022 - Wiley Online Library
Fluorine‐containing moieties are widely used in the pharmaceutical, agrochemical, and
material fields. Thus, these structures are of immense interest in the fields of organic …

Recent developments in organoboron chemistry: old dogs, new tricks

JWB Fyfe, AJB Watson - Chem, 2017 - cell.com
Organoboron reagents are one of the most widely studied and applied classes of reagent
throughout organic synthesis and catalysis. Not only are these reagents integral to many of …

N‐(Acyloxy)phthalimides as Redox‐Active Esters in Cross‐Coupling Reactions

S Murarka - Advanced Synthesis & Catalysis, 2018 - Wiley Online Library
Recent years have witnessed a resurgence of novel, efficient and practical protocols for
radical‐mediated cross‐coupling reactions involving N‐(acyloxy) phthalimides (NHPI esters) …

Catalysis with diboron (4)/pyridine: application to the broad-scope [3+ 2] cycloaddition of cyclopropanes and alkenes

Z Ding, Z Liu, Z Wang, T Yu, M Xu, J Wen… - Journal of the …, 2022 - ACS Publications
In contrast to the extensive but non-recyclable use of tetraalkoxydiboron (4) compounds as
stoichiometric reagents in diverse reactions, this article reports an atom-economical reaction …

Recent advances in the catalytic hydroboration of carbonyl compounds

ML Shegavi, SK Bose - Catalysis Science & Technology, 2019 - pubs.rsc.org
The chemoselective catalytic hydroboration of aldehydes and ketones has found
widespread applications in organic chemistry due to the synthetic utility of borate ester …

Current applications of Suzuki–Miyaura coupling reaction in the total synthesis of natural products: an update

A Taheri Kal Koshvandi, MM Heravi… - Applied …, 2018 - Wiley Online Library
Suzuki‐Miyaura Coupling Reaction (SMCR) has been extensively used in the total synthesis
of natural products. We underscored these achievements in a report published in …