The rise of boron-containing compounds: advancements in synthesis, medicinal chemistry, and emerging pharmacology

RJ Grams, WL Santos, IR Scorei… - Chemical …, 2024 - ACS Publications
Boron-containing compounds (BCC) have emerged as important pharmacophores. To date,
five BCC drugs (including boronic acids and boroles) have been approved by the FDA for …

Metal boranes: Progress and applications

BRS Hansen, M Paskevicius, HW Li, E Akiba… - Coordination Chemistry …, 2016 - Elsevier
Boron and hydrogen have a rich chemistry that has attracted a significant, but mainly
academic, interest during the past century. However, research over the past decades has …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Complex high-temperature phase transitions in Li2B12H12 and Na2B12H12

N Verdal, JH Her, V Stavila, AV Soloninin… - Journal of Solid State …, 2014 - Elsevier
Differential scanning calorimetry measurements of Li 2 B 12 H 12 and Na 2 B 12 H 12
indicate hysteretic transformations to high-temperature phases at≈ 615 K and 529 K …

Halogenated Sodium-closo-Dodecaboranes as Solid-State Ion Conductors

BRS Hansen, M Paskevicius, M Jørgensen… - Chemistry of …, 2017 - ACS Publications
Sodium compounds containing large weakly coordinating anions are explored as ion
conductors. The halogenated sodium-closo-dodecaboranes (Na2B12Cl12, Na2B12Br12 …

High-affinity host–guest chemistry of large-ring cyclodextrins

KI Assaf, D Gabel, W Zimmermann… - Organic & Biomolecular …, 2016 - pubs.rsc.org
The host–guest chemistry of large-ring cyclodextrins (LRCDs) has been largely unexplored
due to the lack of suitable guest molecules that bind with significant affinities to enable …

Boron clusters alter the membrane permeability of dicationic fluorescent DNA-staining dyes

Y Hirai, Y Makita, J Asaoka, Y Aoyagi, A Nomoto… - ACS …, 2023 - ACS Publications
Membrane-permeable fluorescent dyes that stain DNA are useful reagents for microscopic
imaging, as they can be introduced into living cells to label DNA. However, the number of …

Effect of the Presence of Oxysolvents on Compositions and Structures of Silver(I) Complexes with Boron Cluster Anion [B12Cl12]2–

AV Golubev, AS Kubasov, EA Malinina… - Crystal Growth & …, 2024 - ACS Publications
For the first time, a systematic study of the behavior of Ag2 [B12Cl12] in oxygen-containing
organic solvents of various nature (acetone, N, N-dimethylformamide (DMF) …

Synthesis and characterization of synthetically useful salts of the weakly-coordinating dianion [B 12 Cl 12] 2−

V Geis, K Guttsche, C Knapp, H Scherer, R Uzun - Dalton Transactions, 2009 - pubs.rsc.org
The closo-dodecahydrododecaborate [NEt3H] 2 [B12H12] has been prepared on a lab scale
by an improved synthesis from cheap and readily available starting materials Na [BH4] and …

Silver‐Free Activation of Ligated Gold(I) Chlorides: The Use of [Me3NB12Cl11] as a Weakly Coordinating Anion in Homogeneous Gold Catalysis

M Wegener, F Huber, C Bolli, C Jenne… - … –A European Journal, 2015 - Wiley Online Library
Phosphane and N‐heterocyclic carbene ligated gold (I) chlorides can be effectively
activated by Na [Me3NB12Cl11](1) under silver‐free conditions. This activation method with …