Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …
polaritons, are formed due to quantum light–matter interactions. With the experimental …
The rise and current status of polaritonic photochemistry and photophysics
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
Control, modulation, and analytical descriptions of vibrational strong coupling
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …
Molecular chemistry in cavity strong coupling
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …
matter interactions and so-called polaritonic states with intriguing properties, halfway …
Molecular polaritonics: Chemical dynamics under strong light–matter coupling
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …
intense experimental and theoretical studies. Here we review the present status of this field …
Cavity born–oppenheimer hartree–fock ansatz: Light–matter properties of strongly coupled molecular ensembles
Experimental studies indicate that optical cavities can affect chemical reactions through
either vibrational or electronic strong coupling and the quantized cavity modes. However …
either vibrational or electronic strong coupling and the quantized cavity modes. However …
Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …
Cavity-enabled enhancement of ultrafast intramolecular vibrational redistribution over pseudorotation
TT Chen, M Du, Z Yang, J Yuen-Zhou, W **er, M Kowalewski - Journal of Chemical Theory and …, 2023 - ACS Publications
Recent experiments have revealed the profound effect of strong light–matter interactions in
optical cavities on the electronic ground state of molecular systems. This phenomenon …
optical cavities on the electronic ground state of molecular systems. This phenomenon …