Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes

JO Zoppe, NC Ataman, P Mocny, J Wang… - Chemical …, 2017 - ACS Publications
The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-
CRP) techniques has become a powerful approach to tailor the chemical and physical …

Polymer brushes: Synthesis, characterization, properties and applications

AM Bhayo, Y Yang, X He - Progress in Materials Science, 2022 - Elsevier
Polymer brushes are thin polymer films in which the individual polymer chains are tethered
by one chain end to a solid interface. The bulk and solution properties of these highly …

50th Anniversary Perspective: Are Polymer Nanocomposites Practical for Applications?

SK Kumar, BC Benicewicz, RA Vaia, KI Winey - Macromolecules, 2017 - ACS Publications
The field of polymer nanocomposites has been at the forefront of research in the polymer
community for the past few decades. Foundational work published in Macromolecules …

Strong synergistic toughening and compatibilization enhancement of carbon nanotubes and multi-functional epoxy compatibilizer in high toughened polylactic acid …

X Zhao, J Yu, X Wang, Z Huang, W Zhou… - International Journal of …, 2023 - Elsevier
Different carbon nanotubes (CNTs) contents on high-toughness polylactic acid (PLA)/poly
(butylene adipate-co-terephthalate)(PBAT) blends were prepared by one-step melt blending …

Nanocomposites with polymer grafted nanoparticles

SK Kumar, N Jouault, B Benicewicz, T Neely - Macromolecules, 2013 - ACS Publications
A recurring challenge in the field of nanocomposites is to control the spatial distribution of
nanoparticles (NPs) in a polymer matrix. This issue is of critical importance since it is now …

Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications

J Yan, MR Bockstaller, K Matyjaszewski - Progress in Polymer Science, 2020 - Elsevier
Recent progress in surface-initiated polymerization enables the deliberate polymer
modification of nanoscopic surfaces with high levels of precision. This has given rise to the …

Simultaneous Reduction of Bulk and Contact Thermal Resistance in High‐Loading Thermal Interface Materials Using Self‐Assembled Monolayers

X He, X Liu, J Huang, W Lin, J Wen… - Advanced Functional …, 2024 - Wiley Online Library
Thermal interface materials (TIMs) play a pivotal role in the transfer of heat from high‐
temperature sources, such as CPUs, to heat sinks in power electronics. The effectiveness of …

Concepts and conflicts in nanoparticles reinforcement to polymers beyond hydrodynamics

Y Song, Q Zheng - Progress in Materials Science, 2016 - Elsevier
With substantial progresses in reinforcement mechanism of nanoparticle filled polymers
(NPFPs) beyond the hydrodynamic limit, now is the time to reconsider this topic …

Surface-initiated polymerization as an enabling tool for multifunctional (nano-) engineered hybrid materials

CM Hui, J Pietrasik, M Schmitt, C Mahoney… - Chemistry of …, 2014 - ACS Publications
Surface-initiated atom transfer radical polymerization (SI-ATRP) has become an
indispensable tool for engineering the structure and properties of polymer/inorganic and …

Structural, Optical, and Electrical Investigations of Nd2O3-Doped PVA/PVP Polymeric Composites for Electronic and Optoelectronic Applications

SH Zyoud, A Almoadi, TH AlAbdulaal, MS Alqahtani… - Polymers, 2023 - mdpi.com
In this present work, a PVA/PVP-blend polymer was doped with various concentrations of
neodymium oxide (PB-Nd+ 3) composite films using the solution casting technique. X-ray …