Time‐resolved in situ monitoring of mechanochemical reactions

AAL Michalchuk, F Emmerling - … Chemie International Edition, 2022‏ - Wiley Online Library
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …

Mechanochemistry of gaseous reactants

C Bolm, JG Hernández - Angewandte Chemie International …, 2019‏ - Wiley Online Library
In recent years, the application of mechanical energy to chemical systems has repeatedly
proven beneficial to facilitate chemical transformations in various areas in chemistry. Today …

Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring

S Lukin, LS Germann, T Friščić… - Accounts of chemical …, 2022‏ - ACS Publications
Conspectus The past two decades have witnessed a rapid emergence of interest in
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …

Mechanochemistry for organic chemists: an update

D Tan, T Friščić - European Journal of Organic Chemistry, 2018‏ - Wiley Online Library
We provide a brief overview of recent advances in the use of mechanochemical techniques
for the synthesis of organic molecules and materials, highlighting selected examples of …

Methods for monitoring milling reactions and mechanistic studies of mechanochemistry: a primer

PA Julien, T Friščić - Crystal Growth & Design, 2022‏ - ACS Publications
Mechanochemistry by ball milling is garnering significant attention as an efficient and
versatile means of chemical synthesis which minimizes the need for solvents and reduces …

Role of mixing and milling in mechanochemical synthesis

OV Lapshin, EV Boldyreva, VV Boldyrev - Russian Journal of Inorganic …, 2021‏ - Springer
Selected topics of inorganic mechanochemical synthesis are discussed. Variant
mechanochemical syntheses are considered. The ex situ and in situ/operando methods to …

Raman spectroscopy for real-time and in situ monitoring of mechanochemical milling reactions

S Lukin, K Užarević, I Halasz - Nature Protocols, 2021‏ - nature.com
Solid-state milling has emerged as an alternative, sustainable approach for preparing
virtually all classes of compounds and materials. In situ reaction monitoring is essential to …

Outstanding advantages, current drawbacks, and significant recent developments in mechanochemistry: a perspective view

S Pagola - Crystals, 2023‏ - mdpi.com
Although known since antiquity, mechanochemistry has remained dormant for centuries.
Nowadays, mechanochemistry is a flourishing research field at the simultaneous stages of …

C− H bond functionalization by mechanochemistry

JG Hernández - Chemistry–A European Journal, 2017‏ - Wiley Online Library
The advances made in the mechanosynthesis of inorganic and organometallic complexes
and the excellent past developments with metal‐catalyzed cross‐coupling reactions by high …

Controlling the polymorphism and topology transformation in porphyrinic zirconium metal–organic frameworks via mechanochemistry

B Karadeniz, D Žilić, I Huskić… - Journal of the …, 2019‏ - ACS Publications
Tetratopic porphyrin-based metal–organic frameworks (MOFs) represent a particularly
interesting subclass of zirconium MOFs due to the occurrence of several divergent …