We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Electricity originating from renewable resources can be used for highly sustainable and
economically attractive applications. With electrons as the mass-free reagent, the use of a …

Oxidation-induced strategy for inert chemical bond activation through highly active radical
cation intermediate has exhibited unique reactivity. Understanding the structure and …

Constructing photocatalyst systems to functionalize the inert C− H bonds has attracted
extensive research interest. However, purposeful modulation of interfacial charge transfer in …

Conventional designing principal of electrocatalyst is focused on the electronic structure
tuning, on which effectively promotes the electrocatalysis. However, as a typical kind of …

Herein, nickel-catalyzed decarboxylative cross-coupling of indole-3-acetic acids with aryl
bromides by convergent paired electrolysis was developed in an undivided cell. This …

Searching for efficient strategies to access structurally novel aminoindolines is of great
significance for drug discovery. However, catalytic asymmetric de novo construction of …

Abstract A cobalt‐promoted electrochemical 1, 2‐diarylation of alkenes with electron‐rich
aromatic hydrocarbons via direct dual C− H functionalizations is described, which employs a …

Skeletal molecular editing gained considerable recent momentum and emerged as a
uniquely powerful tool for late‐stage diversifications. Thus far, superstoichiometric amounts …

Abstract A direct dearomative photocatalyzed (3+ 2) cycloaddition between indoles and
vinyldiazo reagents is described. The transformation is enabled by the development of a …