Wave mechanics in an ionic liquid mixture

TS Groves, S Perkin - Faraday Discussions, 2024 - pubs.rsc.org
Experimental measurements of interactions in ionic liquids and concentrated electrolytes
over the past decade or so have revealed simultaneous monotonic and oscillatory decay …

Dynamic Ion Correlations and Ion-Pair Lifetimes in Aqueous Alkali Metal Chloride Electrolytes

GR Elliott, EJ Wanless, GB Webber… - The Journal of …, 2024 - ACS Publications
Electrolytes are central to many technological applications, as well as life itself. The behavior
and properties of electrolytes are often described in terms of ion pairs, whereby ions …

[HTML][HTML] Detecting underscreening and generalized Kirkwood transitions in aqueous electrolytes

M Dinpajooh, E Biasin, ET Nienhuis… - The Journal of …, 2024 - pubs.aip.org
We establish the connection between the measured small angle x-ray scattering signal and
the charge–charge correlations underlying Kirkwood transitions (KTs) in 1: 1, 2: 1, and 3: 1 …

Reentrant Condensation of Polyelectrolytes Induced by Diluted Multivalent Salts: The Role of Electrostatic Gluonic Effects

H Yong - Biomacromolecules, 2024 - ACS Publications
We explore the reentrant condensation of polyelectrolytes triggered by multivalent salts,
whose phase-transition mechanism remains under debate. We propose a theory to study the …

Long-Range Surface Forces in Salt-in-Ionic Liquids

X Zhang, ZAH Goodwin, AG Hoane, A Deptula… - ACS …, 2024 - ACS Publications
Ionic liquids (ILs) are a promising class of electrolytes with a unique combination of
properties, such as extremely low vapor pressures and nonflammability. Do** ILs with …

The Polarity of Co-solvents Regulates the Charge Storage Mechanisms in Supercapacitors with Concentrated Electrolytes

ML Martins, T Wang, S Dai… - The Journal of Physical …, 2024 - ACS Publications
Develo** better energy storage devices depends on comprehending the underlying
mechanisms involved in charge storage. With the continuous conception of new electrolytes …

[HTML][HTML] Beyond the Debye–Hückel limit: Toward a general theory for concentrated electrolytes

M Dinpajooh, NN Intan, TT Duignan, E Biasin… - The Journal of …, 2024 - pubs.aip.org
The phenomenon of underscreening in concentrated electrolyte solutions leads to a larger
decay length of the charge–charge correlation than the prediction of Debye–Hückel (DH) …

Cavity correlations and the onset of charge ordering at charged interfaces: A modified Poisson–Fermi approach

OD Braga, T Colla - The Journal of Chemical Physics, 2025 - pubs.aip.org
Charge layering in the close vicinity of charged interfaces is a well-known effect, extensively
reported in both experiments and simulations of Room Temperature Ionic Liquids (RTILs) …

Donnan equilibrium in charged slit-pores from a hybrid nonequilibrium Molecular Dynamics/Monte Carlo method with ions and solvent exchange

J Kim, B Rotenberg - arxiv preprint arxiv:2405.18957, 2024 - arxiv.org
Ion partitioning between different compartments (\emph {eg} a porous material and a bulk
solution reservoir), known as Donnan equilibrium, plays a fundamental role in various …

Length scales in electrolytes

I Skarmoutsos, S Mossa - arxiv preprint arxiv:2409.11179, 2024 - arxiv.org
The elusive presence of an anomalously increasing screening length at high ionic
concentrations hampers a complete picture of interactions in electrolytes. Theories which …