Wave mechanics in an ionic liquid mixture
Experimental measurements of interactions in ionic liquids and concentrated electrolytes
over the past decade or so have revealed simultaneous monotonic and oscillatory decay …
over the past decade or so have revealed simultaneous monotonic and oscillatory decay …
Dynamic Ion Correlations and Ion-Pair Lifetimes in Aqueous Alkali Metal Chloride Electrolytes
Electrolytes are central to many technological applications, as well as life itself. The behavior
and properties of electrolytes are often described in terms of ion pairs, whereby ions …
and properties of electrolytes are often described in terms of ion pairs, whereby ions …
[HTML][HTML] Detecting underscreening and generalized Kirkwood transitions in aqueous electrolytes
We establish the connection between the measured small angle x-ray scattering signal and
the charge–charge correlations underlying Kirkwood transitions (KTs) in 1: 1, 2: 1, and 3: 1 …
the charge–charge correlations underlying Kirkwood transitions (KTs) in 1: 1, 2: 1, and 3: 1 …
Reentrant Condensation of Polyelectrolytes Induced by Diluted Multivalent Salts: The Role of Electrostatic Gluonic Effects
H Yong - Biomacromolecules, 2024 - ACS Publications
We explore the reentrant condensation of polyelectrolytes triggered by multivalent salts,
whose phase-transition mechanism remains under debate. We propose a theory to study the …
whose phase-transition mechanism remains under debate. We propose a theory to study the …
Long-Range Surface Forces in Salt-in-Ionic Liquids
Ionic liquids (ILs) are a promising class of electrolytes with a unique combination of
properties, such as extremely low vapor pressures and nonflammability. Do** ILs with …
properties, such as extremely low vapor pressures and nonflammability. Do** ILs with …
The Polarity of Co-solvents Regulates the Charge Storage Mechanisms in Supercapacitors with Concentrated Electrolytes
Develo** better energy storage devices depends on comprehending the underlying
mechanisms involved in charge storage. With the continuous conception of new electrolytes …
mechanisms involved in charge storage. With the continuous conception of new electrolytes …
[HTML][HTML] Beyond the Debye–Hückel limit: Toward a general theory for concentrated electrolytes
The phenomenon of underscreening in concentrated electrolyte solutions leads to a larger
decay length of the charge–charge correlation than the prediction of Debye–Hückel (DH) …
decay length of the charge–charge correlation than the prediction of Debye–Hückel (DH) …
Cavity correlations and the onset of charge ordering at charged interfaces: A modified Poisson–Fermi approach
OD Braga, T Colla - The Journal of Chemical Physics, 2025 - pubs.aip.org
Charge layering in the close vicinity of charged interfaces is a well-known effect, extensively
reported in both experiments and simulations of Room Temperature Ionic Liquids (RTILs) …
reported in both experiments and simulations of Room Temperature Ionic Liquids (RTILs) …
Donnan equilibrium in charged slit-pores from a hybrid nonequilibrium Molecular Dynamics/Monte Carlo method with ions and solvent exchange
J Kim, B Rotenberg - arxiv preprint arxiv:2405.18957, 2024 - arxiv.org
Ion partitioning between different compartments (\emph {eg} a porous material and a bulk
solution reservoir), known as Donnan equilibrium, plays a fundamental role in various …
solution reservoir), known as Donnan equilibrium, plays a fundamental role in various …
Length scales in electrolytes
The elusive presence of an anomalously increasing screening length at high ionic
concentrations hampers a complete picture of interactions in electrolytes. Theories which …
concentrations hampers a complete picture of interactions in electrolytes. Theories which …