Coinage-metal-based cyclic trinuclear complexes with metal–metal interactions: theories to experiments and structures to functions
Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …
Organometallic polyphosphorus complexes as diversified building blocks in coordination chemistry
The complexes containing cyclo-P n ligands which are π-coordinated to a metal atom have
been known since the late 1970 s. Cyclo-P n ligands being cyclic aromatic P-donors …
been known since the late 1970 s. Cyclo-P n ligands being cyclic aromatic P-donors …
Substituents' Effect on the Photophysics of Trinuclear Copper (I) and Silver (I) Pyrazolate–Phosphine Cages
KF Baranova, AA Titov, JR Shakirova… - Inorganic …, 2024 - ACS Publications
A series of structurally similar trinuclear macrocyclic copper (I) and silver (I) pyrazolate
complexes bearing various short-bite diphosphine R2PCH (R′) PR2 ligands are reported …
complexes bearing various short-bite diphosphine R2PCH (R′) PR2 ligands are reported …
Macrocyclic copper (I) and silver (I) pyrazolates: Principles of supramolecular assemblies with Lewis bases
Macrocyclic copper (I) and silver (I) pyrazolates represent an important class of coordination
compounds used in numerous fundamental areas, such as acid-base chemistry …
compounds used in numerous fundamental areas, such as acid-base chemistry …
Mechanistic study in azide-alkyne cycloaddition (CuAAC) catalyzed by bifunctional trinuclear copper (I) pyrazolate complex: Shift in rate-determining step
Trinuclear copper (I) pyrazolate [Cu (3, 5-(CF 3) 2 Pz)] 3 was employed in a mechanistic
study of azide-alkyne cycloaddition (CuAAC). It was shown that the copper complex …
study of azide-alkyne cycloaddition (CuAAC). It was shown that the copper complex …
Interaction of a trinuclear copper (i) pyrazolate with alkynes and carbon–carbon triple bond activation
The trinuclear copper (I) pyrazolate {[3, 5-(CF3) 2Pz] Cu} 3 forms η2-copper/alkyne triple
bond coordinated structures in the presence of acetylenes. There is no coordination of …
bond coordinated structures in the presence of acetylenes. There is no coordination of …
Luminescent complexes of the trinuclear silver (I) and copper (I) pyrazolates supported with bis (diphenylphosphino) methane
The first example of trinuclear copper (I) and silver (I) pyrazolates adducts with a tertiary
diphosphine (Ph2PCH2PPh2) retaining trimeric [MPz] 3 core is reported. Despite rather …
diphosphine (Ph2PCH2PPh2) retaining trimeric [MPz] 3 core is reported. Despite rather …
Supramolecular design of the trinuclear silver (I) and copper (I) metal pyrazolates complexes with ruthenium sandwich compounds via intermolecular metal− π …
The interaction of copper (I) and silver (I) macrocyclic pyrazolates with aromatic ligands of
ruthenium sandwiches (Cp* RuInd, CpRuInd, and Ind2Ru) in solution is shown for the first …
ruthenium sandwiches (Cp* RuInd, CpRuInd, and Ind2Ru) in solution is shown for the first …
Donor-acceptor electron transfers and bonding performance of cyclopentadienyl and cyclo-P5 middle decks in (CpFeE5) ML3 and (CpFeE5) FeCb (E5= Cp, P5 and …
Density functional theory (DFT) calculations using BP86 and B3LYP* methods have been
applied on a series of isoelectronic (CpFeCp') ML 3,(CpFeP 5) ML 3,(CpFeCp') FeCb and …
applied on a series of isoelectronic (CpFeCp') ML 3,(CpFeP 5) ML 3,(CpFeCp') FeCb and …
The π-acidic coinage-metal cyclic trinuclear complexes with Lewis or π-bases and the relevant applications
Coinage-metal cyclic trinuclear complexes (CTCs) with azolate ligand equipped with strong
electron-withdrawing substituents (eg, CF 3, NO 2) represent the underlying members in the …
electron-withdrawing substituents (eg, CF 3, NO 2) represent the underlying members in the …