50 years ago, Karl Ziegler and Giulio Natta were awarded the Nobel Prize for their discovery
of the catalytic polymerization of ethylene and propylene using titanium compounds and …

Four R1R2Si (OMe) 2 type compounds were added as an external electron donor (De) in
propylene polymerization with TiCl4/Di/MgCl2 type supported Ziegler–Natta catalysts (Di …

A new and effective method for the activation, and simultaneously, immobilization of bis
(phenoxyimine) early‐transition‐metal complexes for olefin polymerization (known as FI …

Kinetics of propylene polymerization with two TiCl4/MgCl2 model catalysts of different Ti
load (Cat‐1: Ti 0.1 wt%; Cat‐2: Ti 1.0 wt%) was investigated in this work. Time‐dependent …

The influence of the structure of external alkoxysilane donors on stereoslectivity and
molecular weight distributions in MgCl2-supported Ziegler–Natta catalysis has been …

Infrared vibrational spectroscopy has been used to reveal the conformations of the Ziegler−
Natta catalysts internal electron donor 9, 9-bis (methoxymethyl)-fluorene and its selectively …

Hexene was polymerized with a commercial MgCl 2-supported Ziegler-Natta catalyst using
triethylaluminum as cocatalyst at different monomer/catalyst mass ratio (m hexene/m cat= 5 …

The catalytic activity and stereospecificity of olefin polymerization by using heterogeneous
TiCl 4/MgCl 2 Ziegler-Natta (ZN) catalysts are determined by the structure and nature of …

Experimental data on the molecular weight distribution (MWD) of polyethylene (PE)
produced over a broad number of Ziegler‐Natta catalysts differing in composition and …

The data on content of individual fractions with different microtacticity for poly
(propylene)(PP) samples produced over titanium–magnesium catalysts (TMCs) with …