It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Transition-metal catalyzed C–H activation reactions have been proven to be useful
methodologies for the assembly of synthetically meaningful molecules. This approach bears …

Ru (II)-catalyzed enantioselective C–H functionalization involving an enantiodetermining C–
H cleavage step remains undeveloped. Here we describe a Ru (II)-catalyzed …

Enantioselective C− H activation has surfaced as a transformative toolbox for the efficient
assembly of chiral molecules. However, despite of major advances in rhodium and …

Satoh–Miura reaction is an important method for extending π‐systems by forging multi‐
substituted benzene rings via double aryl C− H activation and annulation with alkynes …

Challenging enantio-and diastereoselective cobalt-catalyzed C–H alkylation has been
realized by an innovative data-driven knowledge transfer strategy. Harnessing the statistics …

Sulfur-stereogenic containing benzo-fused heterocycles have gained much attention in drug
discovery. However, the asymmetric synthesis of these chiral molecules with structural …

An unprecedented enantioselective synthesis of spiro‐γ‐lactams via a sequential C− H
olefination/asymmetric [4+ 1] spirocyclization under a simple CoII/chiral spiro phosphoric …

Sulfondiimines are diaza‐analogues of sulfones with a chiral sulfur center. Compared to
sulfones and sulfoximines, their synthesis and transformations have so far been studied to a …

Developed herein is a chiral sulfoximine-enabled Ru (II)-catalyzed asymmetric C–H
activation/functionalization involving intramolecular hydroarylation and functionalization …