Palladium-catalyzed carbonylative coupling reactions of aromatic halides and related
compounds have undergone a rapid development during recent years. Nowadays, a …

The regioselective functionalization of terminal alkenes and alkynes is of utmost importance
for the synthesis of a wide variety of organic products. Based on the original observation by …

Palladium‐catalyzed coupling reactions have become a powerful tool for advanced organic
synthesis. This type of reaction is of significant value for the preparation of pharmaceuticals …

Palladium‐catalyzed carbonylation reactions of alkenes and alkynes with different
nucleophiles have undergone rapid development ever since the seminal work of Reppe …

Various olefins can be smoothly transformed in the presence of a Pd‐based catalyst system
and (hetero) aromatic amines or nitroarenes to synthetically interesting amides in good …

Palladium-catalyzed carbonylation is a versatile method for the synthesis of various
aldehydes, esters, lactones, or lactams. Alkoxycarbonylation of alkenes with carbon …

Reaktionen zur selektiven Veredelung von Alkenen zählen zu den wichtigsten Methoden in
der Organischen Synthese. Durch die Entwicklung von Übergangsmetallkatalysatoren in …

The mechanism and kinetics of the solvolysis of complexes of the type [(L− L) Pd (C (O)
CH3)(S)]+[CF3SO3]-(L− L= diphosphine ligand, S= solvent, CO, or donor atom in the ligand …

Alkoxycarbonylation reactions are common in the chemical industry, yet process
sustainability is limited by the inefficient utilization of CO. In this study, we address this issue …

Carbonylation reactions often suffer from catalyst deactivation. Operando spectroscopy has
been proven to be a suitable tool for both understanding deactivation mechanisms and …