High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Spin crossover (SCO) complexes are classic magnetic bistable materials with various
promising potential applications, such as data storage, displays, switches, actuators and …

Spin-crossover (SCO) coordination cages are at the forefront of research for their potential in
crafting next-generation molecular devices. However, due to the scarcity of SCO hosts and …

The use of copper (I) in metal–organic assemblies leads readily to the formation of simple
grids and helicates, whereas higher-order structures require complex ligand designs. Here …

Confinement of discrete coordination cages within nanoporous lattices is an intriguing
strategy to gain unusual properties and functions. We demonstrate here that the confinement …

We derive design principles for the assembly of rectangular tetramines into Zn8L6 pseudo‐
cubic coordination cages. Because of the rectangular, as opposed to square, geometry of …

The effect of host–guest interactions on the chemistry of encapsulated molecules is a
fascinating field of research that has gained momentum in recent years. Much of the work in …

Porous structures based on multi-metallic motifs are receiving growing interest, but their
general preparation still remains a challenge. Here, we report the self-assembly and …

Supramolecular architectures, which are formed through the combination of inorganic metal
cations and organic ligands by self-assembly, are one of the techniques in modern chemical …

There is a concerted attempt to develop self‐assembled metallo‐cages of greater structural
complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts …