Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
S Kuriyama, K Arashiba, K Nakajima, Y Matsuo… - Nature …, 2016 - nature.com
Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied,
because the iron atom plays an important role in the industrial and biological nitrogen …
because the iron atom plays an important role in the industrial and biological nitrogen …
Radical‐type reactivity and catalysis by single‐electron transfer to or from redox‐active ligands
JI van der Vlugt - Chemistry–A European Journal, 2019 - Wiley Online Library
Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …
importance for selective (catalytic) processes. This Concept aims to provide an overview of …
Tridentate pyridine–pyrrolide chelate ligands: An under-appreciated ligand set with an immensely promising coordination chemistry
This review covers all aspects of the chemistry of metal complexes of tridentate κ 3-N
pyridine–pyrrolide ligands, from the syntheses of the ligands to what is known about the …
pyridine–pyrrolide ligands, from the syntheses of the ligands to what is known about the …
Redox noninnocent azo-aromatic pincers and their iron complexes. Isolation, characterization, and catalytic alcohol oxidation
The new redox-noninnocent azoaromatic pincers 2-(arylazo)-1, 10-phenanthroline (L1) and
2, 9-bis (phenyldiazo)-1, 10-phenanthroline (L2) are reported. The ligand L1 is a tridentate …
2, 9-bis (phenyldiazo)-1, 10-phenanthroline (L2) are reported. The ligand L1 is a tridentate …
Chemical and Redox Noninnocence of Pentane-2,4-dione Bis(S-methylisothiosemicarbazone) in Cobalt Complexes and Their Application in Wacker-Type Oxidation
V Porte, MNM Milunovic, U Knof, T Leischner, T Danzl… - JACS Au, 2024 - ACS Publications
Cobalt complexes with multiproton-and multielectron-responsive ligands are of interest for
challenging catalytic transformations. The chemical and redox noninnocence of pentane-2 …
challenging catalytic transformations. The chemical and redox noninnocence of pentane-2 …
Snapshot of cyclooctyne ring-opening to a tethered alkylidene cyclic polymer catalyst
Cyclooctyne reacts with the trianionic pincer ligand supported alkylidyne [tBuOCO] WCC
(CH3) 3 (THF) 2 (1) to yield tungstacyclopropene (3) and tungstacyclopentadiene (4) …
(CH3) 3 (THF) 2 (1) to yield tungstacyclopropene (3) and tungstacyclopentadiene (4) …
Control of Ligand pKa Values Tunes the Electrocatalytic Dihydrogen Evolution Mechanism in a Redox-Active Aluminum(III) Complex
Redox-active ligands bring electron-and proton-transfer reactions to main-group
coordination chemistry. In this Forum Article, we demonstrate how ligand p K a values can …
coordination chemistry. In this Forum Article, we demonstrate how ligand p K a values can …
An azoaromatic ligand as four electron four proton reservoir: catalytic dehydrogenation of alcohols by its zinc (II) complex
Electroprotic storage materials, though invaluable in energy-related research, are scanty
among non-natural compounds. Herein, we report a zinc (II) complex of the ligand 2, 6-bis …
among non-natural compounds. Herein, we report a zinc (II) complex of the ligand 2, 6-bis …
Ligand centered redox enabled sustainable synthesis of triazines and pyrimidines using a zinc-stabilized azo-anion radical catalyst
Herein, we report ligand-centered redox controlled Zn (II)-catalyzed multicomponent
approaches for synthesizing pyrimidines and triazines. Taking advantage of the ligand …
approaches for synthesizing pyrimidines and triazines. Taking advantage of the ligand …
Deprotonation Induced Ligand Oxidation in a NiII Complex of a Redox Noninnocent N1-(2-Aminophenyl)benzene-1,2-diamine and Its Use in Catalytic Alcohol …
Two nickel (II)-complexes,[NiII (H3L) 2](ClO4) 2 ([1](ClO4) 2) and [NiII (HL) 2](2), containing
the redox-active tridentate ligand N 1-(2-aminophenyl) benzene-1, 2-diamine (H3L) have …
the redox-active tridentate ligand N 1-(2-aminophenyl) benzene-1, 2-diamine (H3L) have …