On the nature of the active species in palladium catalyzed Mizoroki–Heck and Suzuki–Miyaura couplings–homogeneous or heterogeneous catalysis, a critical review

NTS Phan, M Van Der Sluys… - Advanced Synthesis & …, 2006 - Wiley Online Library
A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …

Organic polymer supports for synthesis and for reagent and catalyst immobilization

J Lu, PH Toy - Chemical reviews, 2009 - ACS Publications
Merrifield first reported the concept of solid-phase peptide synthesis using heterogeneous
chloromethylated polystyrene that was lightly cross-linked by divinylbenzene (Merrifield …

Mesoporous silica-supported Pd catalysts: An investigation into structure, activity, leaching and heterogeneity

JD Webb, S MacQuarrie, K McEleney, CM Crudden - Journal of Catalysis, 2007 - Elsevier
Mesoporous silica functionalized by mercaptopropyl trimethoxysilane can be loaded with
palladium and the resulting material used as a catalyst for a variety of coupling reactions …

Mizoroki− Heck coupling using immobilized molecular precatalysts: Leaching active species from Pd pincers, entrapped Pd salts, and Pd NHC complexes

M Weck, CW Jones - Inorganic chemistry, 2007 - ACS Publications
The Mizoroki− Heck reaction is a palladium-catalyzed reaction of both practical importance
and scientific significance. Two challenges currently faced by practitioners of the Heck and …

[SÁCH][B] Micro reaction technology in organic synthesis

C Wiles, P Watts - 2016 - books.google.com
A valuable resource for the modern synthetic chemist, this broadly applicable book
addresses the multidisciplinary field of micro reaction technology-from novel research …

Toward a Continuous‐Flow Synthesis of Boscalid®

TN Glasnov, CO Kappe - Advanced Synthesis & Catalysis, 2010 - Wiley Online Library
A two‐step continuous‐flow protocol for the synthesis of 2‐amino‐4′‐chlorobiphenyl, a key
intermediate for the industrial preparation of the fungicide Boscalid® is described. Initial …

Microflow chemistry and its electrification for sustainable chemical manufacturing

TY Chen, YW Hsiao, M Baker-Fales, F Cameli… - Chemical …, 2022 - pubs.rsc.org
Sustainability is vital in solving global societal problems. Still, it requires a holistic view by
considering renewable energy and carbon sources, recycling waste streams …

Macroporous Polystyrene-Supported Palladium Catalyst Containing a Bulky N-Heterocyclic Carbene Ligand for Suzuki Reaction of Aryl Chlorides

DH Lee, JH Kim, BH Jun, H Kang, J Park, YS Lee - Organic letters, 2008 - ACS Publications
Macroporous polystyrene (MPS)-supported 1-mesitylimidazolium chloride resin was
prepared by reacting macroporous chloromethyl polystyrene with 1-mesitylimidazole as a …

Recent Advancements in Continuous‐Flow Suzuki‐Miyaura Coupling Utilizing Immobilized Molecular Palladium Complexes

Z Zhang, YMA Yamada - Chemistry–A European Journal, 2024 - Wiley Online Library
Abstract Immobilized Pd‐catalyzed Suzuki‐Miyaura coupling under continuous‐flow
conditions using a packed‐bed reactor, representing an efficient, automated, practical, and …

Poly (4‐vinylpyridine) and Quadrapure TU as Selective Poisons for Soluble Catalytic Species in Palladium‐Catalyzed Coupling Reactions–Application to Leaching …

JM Richardson, CW Jones - Advanced Synthesis & Catalysis, 2006 - Wiley Online Library
Abstract Poly (4‐vinylpyridine) and Quadrapure TU were successfully used as poisons for
palladium‐catalyzed Heck couplings of iodoarenes and n‐butyl acrylate using a poly (urea) …