Micellar solutions as reaction media

S Ta - Tetrahedron, 1996 - Elsevier
It is well established that, in many cases, rates and pathways of all kinds of chemical
reactions can be altered by performing the reactions in micellar media instead of pure bulk …

Interactions of neutral molecules with ionic micelles

L Sepulveda, E Lissi, F Quina - Advances in colloid and interface science, 1986 - Elsevier
The interactions of neutral molecules with ionic micelles are analyzed. The cell and mass
action models are presented in order to provide a semi-quantitative description of the …

Organic reactivity in aqueous micelles and similar assemblies

CA Bunton, G Savelli - Advances in Physical Organic Chemistry, 1986 - Elsevier
Publisher Summary This chapter discusses thermal reactions in aqueous colloidal systems.
It aims is to analyze the reactions from a mechanistic point of view, and therefore discussion …

Iterative calculation method for determining the effect of counterions on acetylsalicylate ester hydrolysis in cationic micelles

E Rodenas, S Vera - The Journal of Physical Chemistry, 1985 - ACS Publications
The fractionof micellar surface neutralized is calculated from kinetic results considering
independent distribution equilibria between aqueous and micellar pseudophases for …

Inhibiton effect of cationic micelles on the basic hydrolysis of aromatic esters

S Vera, E Rodenas - Tetrahedron, 1986 - Elsevier
The basic hydrolysis of 4-acetoxybenzoic acid and 2-naphtyl-acetate have been studied in
cationic micelles of N-cetyl-N, N, N-tri-methylaamonium bromide and hydroxide and the …

Optimization and Enhancement of the Peroxidase-like Activity of Hemin in Aqueous Solutions of Sodium Dodecylsulfate

N Cvjetan, LD Schuler, T Ishikawa, P Walde - ACS omega, 2023 - ACS Publications
Iron porphyrins play several important roles in present-day living systems and probably
already existed in very early life forms. Hemin (= ferric protoporphyrin IX= ferric heme b), for …

Kemp elimination in membrane mimetic reaction media: probing catalytic properties of catanionic vesicles formed from double-tailed amphiphiles

JE Klijn, JBFN Engberts - Journal of the American Chemical …, 2003 - ACS Publications
The rate-determining deprotonation of 5-nitrobenzisoxazole (Kemp elimination) by
hydroxide is efficiently catalyzed by vesicles formed from dimethyldioctadecylammonium …

Physical properties of dodecyltrimethylammonium bromide (DTAB) micelles in aqueous solution and their behavior as the reaction medium

E Rodenas, C Dolcet, M Valiente, EC Valeron - Langmuir, 1994 - ACS Publications
The influence of dodecyltrimethylammonium bromide (DTAB) micelles in aqueous solution
on the basic hydrolysis of a positively charged (crystal violet) and a negatively charged …

Factors influencing the micellar catalyzed hydrolysis of long-chain alkyl betainates

RA Thompson, S Allenmark - Journal of colloid and interface science, 1992 - Elsevier
Radiolabeled compounds were used to study and compare the hydrolysis rates of long-and
short-chain alkyl betainates (alkoxycarbonyl-N, N, N-trimethylmethanaminium chlorides) …

Ion binding and micellar effects upon reactions of carboxylic anhydrides and carbonate esters

H Al-Lohedan, CA Bunton - The Journal of Organic Chemistry, 1982 - ACS Publications
Cationic micelles speed reactions of benzoic anhydride and bis (4-nitrophenyl) carbonate
with hydroxide and carboxylate ion. With micellized cetyltrimethylammonium bromide …