Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Electron microscopy allows the extraction of multidimensional spatiotemporally correlated
structural information of diverse materials down to atomic resolution, which is essential for …

An energy decomposition analysis method is implemented for the analysis of both covalent
bonds and intermolecular interactions on the basis of single-determinant Hartree–Fock …

Metal–organic frameworks (MOFs) are unique hybrid porous materials formed by combining
metal ions or clusters with organic ligands. Thiol and thioether-based MOFs belong to a …

Chemical reactivity underlies our fundamental understanding of many physical and
biological phenomena. Chemical reactions are typically initiated by heat, electric current or …

Zinc is more widely used as a cofactor in proteins than any other transition metal ion. In
addition to catalytic and structural functions, zinc (II) ions have a role in information transfer …

Metallo dithiolene complexes with biological and catalytic relevance are well-known for
having strong metal–ligand covalency, which dictates their valence electronic structures. We …

Conspectus Sulfur-rich metalloproteins and metalloenzymes, containing strongly covalent
metal–thiolate (cysteinate) or metal–sulfide bonds in their active site, are ubiquitous in …

Metallothioneins (MTs) are low-molecular-mass cysteine-rich proteins with the ability to bind
mono-and divalent metal ions with the electron configuration d 10 in form of metal-thiolate …

Nickel (Ni (Sal CF3)) and copper (Cu (Sal CF3)) complexes of an electron-poor salen ligand
were prepared, and their one-electron oxidized counterparts were studied using an array of …