The continuously increasing need for novel and selective methods in organic synthesis to
aid drug discovery and to address environmental concerns is a constant source of …

Careful analysis and comparison of the available acidity data of HCl, HBr, HI, HClO4, and
CF3SO3H in water, dimethyl sulfoxide (DMSO), and gas-phase has been carried out. The …

The equilibrium acidity scale (pKa scale) in acetonitrile has been supplemented by
numerous new compounds and new ΔpKa measurements. It now contains altogether 231 …

Acidities of different families of acids are examined in media of different physical and
chemical nature: water, acetonitrile (AN), 1, 2‐dichloroethane (DCE) and the gas phase, with …

In this paper, we report the most comprehensive equilibrium superacidity scale that is
available to date. Contrary to most of the past works, this scale is set up in a medium of …

13 4-NO2-C6H4-SO2CH (CN) 2-0.82 0.07 6.06 [f] 5.24 5.2 2, 4, 6-(SO2F) 3 Phenol-0.47
0.03 5.53 [f] 5.06 a Calculated difference between the pKa values of the reference acid and …

The most comprehensive solvent acidity scale spanning 28 orders of magnitude of acidity
was measured in the low-polarity solvent 1, 2-dichloroethane (DCE). Its experimental core is …

The ionicity and transport properties of a series of diethylmethylamine (DEMA) based protic
ionic liquids (PILs) were characterized, principally utilizing nuclear magnetic resonance …

Der steigende Bedarf an neuen selektiven und umweltverträglichen Methoden in der
organischen Synthese treibt die Entwicklung effizienterer Reaktionssysteme an. In diesem …

Liquid structures of the bis (trifluoromethanesulfonyl) amide based ionic liquids composed of
1-ethyl-3-methylimidazolium and N-methyl-N-propylpyrrolidinium ([C2mIm+][TFSA–] and …