Molecular reactions at aqueous interfaces
MF Ruiz-Lopez, JS Francisco… - Nature Reviews …, 2020 - nature.com
This Review aims to critically analyse the emerging field of chemical reactivity at aqueous
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …
Spontaneous reduction-induced degradation of viologen compounds in water microdroplets and its inhibition by host–guest complexation
C Gong, D Li, X Li, D Zhang, D **ng… - Journal of the …, 2022 - ACS Publications
Water serves as an inert environment for the dispersion and application of many kinds of
herbicides. Viologen compounds, a type of widely used but highly toxic herbicide, are stable …
herbicides. Viologen compounds, a type of widely used but highly toxic herbicide, are stable …
Heterogeneous reactions of volatile organic compounds in the atmosphere
Volatile organic compounds (VOCs) are of central importance in the atmosphere because of
their close relation to air quality and climate change. As a significant sink for VOCs, the fate …
their close relation to air quality and climate change. As a significant sink for VOCs, the fate …
On the formation of hydrogen peroxide in water microdroplets
Recent reports on the formation of hydrogen peroxide (H2O2) in water microdroplets
produced via pneumatic spraying or capillary condensation have garnered significant …
produced via pneumatic spraying or capillary condensation have garnered significant …
Electrification at water–hydrophobe interfaces
The mechanisms leading to the electrification of water when it comes in contact with
hydrophobic surfaces remains a research frontier in chemical science. A clear …
hydrophobic surfaces remains a research frontier in chemical science. A clear …
Acids at the edge: Why nitric and formic acid dissociations at air–water interfaces depend on depth and on interface specific area
Whether the air–water interface decreases or increases the acidity of simple organic and
inorganic acids compared to the bulk is critically important in a broad range of environmental …
inorganic acids compared to the bulk is critically important in a broad range of environmental …
Free-energy barriers and reaction mechanisms for the electrochemical reduction of CO on the Cu (100) surface, including multiple layers of explicit solvent at pH 0
The great interest in the photochemical reduction from CO2 to fuels and chemicals has
focused attention on Cu because of its unique ability to catalyze formation of carbon …
focused attention on Cu because of its unique ability to catalyze formation of carbon …
Fenton chemistry at aqueous interfaces
S Enami, Y Sakamoto… - Proceedings of the …, 2014 - National Acad Sciences
In a fundamental process throughout nature, reduced iron unleashes the oxidative power of
hydrogen peroxide into reactive intermediates. However, notwithstanding much work, the …
hydrogen peroxide into reactive intermediates. However, notwithstanding much work, the …
Brønsted basicity of the air–water interface
H Mishra, S Enami, RJ Nielsen… - Proceedings of the …, 2012 - National Acad Sciences
Differences in the extent of protonation of functional groups lying on either side of water–
hydrophobe interfaces are deemed essential to enzymatic catalysis, molecular recognition …
hydrophobe interfaces are deemed essential to enzymatic catalysis, molecular recognition …
Oxidation of Gas-Phase SO2 on the Surfaces of Acidic Microdroplets: Implications for Sulfate and Sulfate Radical Anion Formation in the Atmospheric Liquid Phase
HM Hung, MR Hoffmann - Environmental Science & Technology, 2015 - ACS Publications
The oxidation of SO2 (g) on the interfacial layers of microdroplet surfaces was investigated
using a spray-chamber reactor coupled to an electrospray ionization mass spectrometer …
using a spray-chamber reactor coupled to an electrospray ionization mass spectrometer …